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An example of ambidentate ligand is...

An example of ambidentate ligand is

A

`H_2 O`

B

`NO_2^-`

C

`NH_2CH_2CH_2NH_2`

D

`NH_3`

Text Solution

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The correct Answer is:
To determine an example of an ambidentate ligand, we need to understand what ambidentate ligands are and identify a suitable example. ### Step-by-Step Solution: 1. **Definition of Ambidentate Ligands**: Ambidentate ligands are ligands that have two different atoms that can donate electrons to a central metal atom or ion. These ligands can bind to the metal through either of the two donor atoms. **Hint**: Remember that ambidentate ligands must have at least two different donor atoms. 2. **Examples of Ligands**: - Water (H2O) is a common ligand, but it only has one donor atom (oxygen), so it cannot be ambidentate. - The nitrito ligand (NO2-) is a good example of an ambidentate ligand because it can donate electrons from either the nitrogen atom or the oxygen atom. **Hint**: Look for ligands that can coordinate through different atoms. 3. **Understanding Nitrito (NO2-)**: - In the nitrito ion (NO2-), the oxygen atom can donate a pair of electrons to the metal, or the nitrogen atom can also donate a pair of electrons. This dual capability makes it ambidentate. - When it donates through oxygen, it is called "nitrito-O", and when it donates through nitrogen, it is called "nitrito-N". **Hint**: Consider how the structure of the ligand allows for different atoms to participate in bonding. 4. **Conclusion**: Based on the above analysis, the nitrito ion (NO2-) is an example of an ambidentate ligand because it has two different donor atoms (N and O) that can coordinate with a metal center. **Final Answer**: An example of an ambidentate ligand is **NO2- (nitrito)**.
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Knowledge Check

  • An example of bidentate ligand is

    A
    Ethylene triamine
    B
    Cyanide ion
    C
    Ethylene diamine
    D
    EDTA
  • An example of bidenatate ligand is

    A
    `NH_(3)`
    B
    `OH^(-)`
    C
    `"ox"^(2-)`
    D
    `Cl^(-)`
  • An example of non ambidentate ligand is

    A
    `NH_(3)`
    B
    SCN
    C
    CN
    D
    `NO_(2)`
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