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Ethylidene chloride is a/an...

Ethylidene chloride is a/an

A

Gem-dihalide

B

Allylic halide

C

Vinylic halide

D

Vic-dihalide

Text Solution

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The correct Answer is:
To determine the classification of ethylidene chloride, we need to analyze its structure and compare it with the definitions of the different types of halides provided in the options. ### Step-by-Step Solution: 1. **Understand the Structure of Ethylidene Chloride**: - Ethylidene chloride has the chemical formula C2H4Cl2. It consists of a two-carbon chain (ethyl) with two chlorine atoms attached. 2. **Identify the Type of Dihalide**: - We need to classify ethylidene chloride based on the position of the chlorine atoms relative to the carbon atoms in the molecule. 3. **Definitions of Halides**: - **Geminal Dihalide**: Both halogens are attached to the same carbon atom. - **Vicinal Dihalide**: The halogens are attached to adjacent carbon atoms. - **Allylic Halide**: The halogen is attached to a carbon that is adjacent to a carbon-carbon double bond. - **Vinylic Halide**: The halogen is attached directly to a carbon that is part of a carbon-carbon double bond. 4. **Analyzing Ethylidene Chloride**: - In ethylidene chloride, the two chlorine atoms are attached to the same carbon atom (the first carbon in the ethyl group). This matches the definition of a geminal dihalide. 5. **Conclusion**: - Based on the analysis, ethylidene chloride is classified as a **geminal dihalide**. ### Final Answer: Ethylidene chloride is a **geminal dihalide**. ---
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In the following questions, a statement of assertion (A) is following by a statement of reason (R ) A : Ethylidene chloride on alkaline hydrolysis gives acetaidehyde. R: Two chlorine atoms attached with adjacent carbon atom in alkylidene chloride .

Statement-I: Acetylene is formed when ethylene chloride or ethylidene chloride is heated with alcoholic KOH. Statement-II: Both gem dihalides and vinicinal dihalides on dehydrohalogenation form alkyne.

Knowledge Check

  • Assertion: Common name of 1,1-dichloroethane is ethylidene chloride. Reason: Ethylidene chloride is a gem-dihalide.

    A
    If both assertion and reason are true and reason Is the correct explanation of assertion.
    B
    If both assertion and reason are true but reason is not the correct explanation of assertion.
    C
    If assetion is true but reason is false.
    D
    If both assertion and reason are false.
  • Ethylidene chloride is hydrolysed with aqueous NaOH. The product formed is:

    A
    Ethanol
    B
    Ethanal
    C
    Ethanone
    D
    Ethane
  • Ethylidene chloride is formed by treating acetylene wit:

    A
    HCl
    B
    `Cl_(2)` in the presence of `C Cl_(4)`
    C
    HOCl
    D
    `Cl_(2)` in presnce of organic peroxide
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    Ethylidene chloride on treatment with aqueous KOH gives ?

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    Ethylidene chloride can be prepared by the reaction of HCI and