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Explain the following : Pb^(4+) acts ...

Explain the following :
`Pb^(4+)` acts as an oxidizing agent but `Sn^(2+)` acts as a reducing agent .

Text Solution

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`Pb^(4+)` by gaining 2 electrons changes into `Pb^(2+)` which is more stable due to inert pair effect . `Sn^(2+)` is less stable than `Sn^(4+)` by losing electrons. Therefore , `Pb^(4+)` acts as an oxidizing agent while `Sn^(2+)` acts as a reducing agent.
`Sn^(2+) to Sn^(+4) + 2e^(-)`
`Pb^(4+) + 2e^(-) to Pb^(2+)`
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Knowledge Check

  • Which of the following will not act as oxidising agents?

    A
    `CrO_(3)`
    B
    `MoO_(3)`
    C
    `WO_(3)`
    D
    `CrO_(4)^(2-)`
  • Which of the following is not an oxidizing agent ?

    A
    Lithium aluminium hydride
    B
    Pyridinium chlorochromate
    C
    `CrO_(3)//H_(2)SO_(4)`
    D
    Alkaline `KMnO_(4)`
  • Which of the following is not an oxidizing agent ?

    A
    `SO_(2)`
    B
    `H_(2)SO_(4)`
    C
    `HNO_(3)`
    D
    `H_(3)PO_(4)`
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