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In the representation of specific rotati...

In the representation of specific rotation `([alpha]_(D)^(250C))`, .D. indicates

A

Dextro rotation

B

Configuration of -OH group

C

Configuration of `-NH_2` group

D

Wave length of light

Text Solution

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The correct Answer is:
D

Wave length of light
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D(+) Glucose has melting point 140^(@)C and specific rotation [a]_(D)^(25) is 112^(@)C . Another D(+) Glucose has melting point 150^(@)C and specific rotation [a]_(D)^(25) is +18.7^(@)C . The two form have significantly different optical rotation but when an aqueous solution of either form is allowed to stand, it rotation changes. The specific rotation of one form decreases and rotation of other increases until both solution show the same value +52.7^(@) . The change in rotation towards an equilibrium value is called mutarotation [alpha]_(D)^(25) = +18.7^(@)C " " [alpha]_(D)^(25) = +112^(@)C Mutarotation is characteristic feature of

D(+) Glucose has melting point 140^(@)C and specific rotation [a]_(D)^(25) is 112^(@)C . Another D(+) Glucose has melting point 150^(@)C and specific rotation [a]_(D)^(25) is +18.7^(@)C . The two form have significantly different optical rotation but when an aqueous solution of either form is allowed to stand, it rotation changes. The specific rotation of one form decreases and rotation of other increases until both solution show the same value +52.7^(@) . The change in rotation towards an equilibrium value is called mutarotation [alpha]_(D)^(25) = +18.7^(@)C " " [alpha]_(D)^(25) = +112^(@)C What percentage of beta-D-(+) glucopyranose found at equilibrium in the aqueous solution?

Knowledge Check

  • For an optically active compound specific rotation ([alpha]_(D)^(25)) depends on a) Length of the polarimeter tube b)Concentration of solution c) Polarimeter instrument d) Nature of the compound

    A
    All
    B
    Only b and c
    C
    Only a and c
    D
    a,b,d
  • Freshly prepared alpha-D- glucose solution has specific rotation +111^(@) and after sometime it becomes

    A
    `+52^(@)`
    B
    `+99^(@)`
    C
    `-92^(@)`
    D
    None
  • Freshly prepared a-D-glucose solution has specific rotation +111^(@) and after sometime it becomes

    A
    `+52^(@)`
    B
    `+99^(@)`
    C
    `-92^(@)`
    D
    None
  • Similar Questions

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    D(+) Glucose has melting point 140^(@)C and specific rotation [a]_(D)^(25) is 112^(@)C . Another D(+) Glucose has melting point 150^(@)C and specific rotation [a]_(D)^(25) is +18.7^(@)C . The two form have significantly different optical rotation but when an aqueous solution of either form is allowed to stand, it rotation changes. The specific rotation of one form decreases and rotation of other increases until both solution show the same value +52.7^(@) . The change in rotation towards an equilibrium value is called mutarotation [alpha]_(D)^(25) = +18.7^(@)C " " [alpha]_(D)^(25) = +112^(@)C For mannose the mutarotation can be shown in brief as follow

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