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An alkaline earth metal (M) gives a salt...

An alkaline earth metal (M) gives a salt chlorine, which is souble in water at room temperature. It also forms an insoluble sulphate whose mixture with a sulphide of a transtion metal is called lithopone a while pigment Metal M is

A

Ca

B

Mg

C

Ba

D

Sr

Text Solution

Verified by Experts

The correct Answer is:
A

Lithopone can be formed by calcium
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BeO and Be(OH)_(2) are amphoteric while the oxides and hydroxides of other alkaline earth metals are basic. The solubility of hydroxides increases as we move down the group from Be to Ba but the solubility of sulphates and carbonates decreases in that order the thermal stability of carbonates and sulphates of alkaline earth metals increases from Be to Ba as we move from top to bottom in the group. The solubility in water of sulphates down the Be group is Be gt Mg gt Ca gt Sr gt Ba this is due to

BeO and Be(OH)_(2) are amphoteric while the oxides and hydroxides of other alkaline earth metals are basic. The solubility of hydroxides increases as we move down the group from Be to Ba but the solubility of sulphates and carbonates decreases in that order the thermal stability of carbonates and sulphates of alkaline earth metals increases from Be to Ba as we move from top to bottom in the group. Which of the following is strongest base ?

Knowledge Check

  • A metal M readily forms its sulphate MSO_(4) which is water soluble. It forms oxide Mo which becomes inert on heating. It forms insouble hydroxide which is soluble NaOH. The metal is

    A
    Mg
    B
    Ba
    C
    Ca
    D
    Be
  • Passage-I : Metallic sulphates can be obtained by reacting the metals (above hydrogen in ECS), or its oxide, hydroxide or carbonate with dil. H_(2)SO_(4) . Group IA metals also form hydrogen sulphates which can be isolated in solid. In general metal sulphates are soluble in water and crystallize with water of crystallization. Sulphates are thermally more stable than nitrates. Among the metals given below, which metal will not give its sulphate on treatment with dil. H_(2)SO_(4) .

    A
    Ni
    B
    Cr
    C
    Co
    D
    Cu
  • BeO and Be(OH)_(2) are amphoteric while the oxides and hydroxides of other alkaline earth metals are basic. The solubility of hydroxides increases as we move down the group from Be to Ba but the solubility of sulphates and carbonates decreases in that order the thermal stability of carbonates and sulphates of alkaline earth metals increases from Be to Ba as we move from top to bottom in the group. Which of the following metal carbonates decompses on heating ?

    A
    `MgCO_(3)`
    B
    `Na_(2)CO_(3)`
    C
    `K_(2)CO_(3)`
    D
    `Rb_(2)CO_(3)`
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    Passage-I : Metallic sulphates can be obtained by reacting the metals (above hydrogen in ECS), or its oxide, hydroxide or carbonate with dil. H_(2)SO_(4) . Group IA metals also form hydrogen sulphates which can be isolated in solid. In general metal sulphates are soluble in water and crystallize with water of crystallization. Sulphates are thermally more stable than nitrates. Select the stable hydrogen sulphate which can be obtained in solid state:

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