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The equation of a state of a gas is give...

The equation of a state of a gas is given by `p(V-b)=nRT`. If 1 mole of a gas is isothermally expanded from volume V and 2V, the work done during the process is

A

(a) `RT ln|(2V-b)/(V-b)|`

B

(b) `RT ln|(V-b)/(V)|`

C

(c) `RT In|(V-b)/(2V-b)|`

D

(d) `RT In|(V)/(V-b)|`

Text Solution

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The correct Answer is:
To solve the problem, we need to calculate the work done during the isothermal expansion of 1 mole of gas from volume \( V \) to \( 2V \) using the given equation of state \( p(V-b) = nRT \). ### Step-by-Step Solution: 1. **Identify the equation of state**: The equation is given as: \[ p(V - b) = nRT \] Rearranging this gives us the pressure \( p \): \[ p = \frac{nRT}{V - b} \] 2. **Set up the work done formula**: The work done \( W \) during an isothermal expansion is given by the integral: \[ W = \int_{V}^{2V} p \, dV \] Substituting the expression for \( p \): \[ W = \int_{V}^{2V} \frac{nRT}{V - b} \, dV \] 3. **Take constants out of the integral**: Since \( nRT \) is constant for this process (1 mole of gas at constant temperature), we can factor it out of the integral: \[ W = nRT \int_{V}^{2V} \frac{1}{V - b} \, dV \] 4. **Evaluate the integral**: The integral of \( \frac{1}{V - b} \) is: \[ \int \frac{1}{V - b} \, dV = \ln |V - b| \] Therefore, we evaluate the definite integral: \[ W = nRT \left[ \ln |V - b| \right]_{V}^{2V} \] This gives: \[ W = nRT \left( \ln |2V - b| - \ln |V - b| \right) \] 5. **Simplify using properties of logarithms**: Using the property of logarithms \( \ln a - \ln b = \ln \frac{a}{b} \): \[ W = nRT \ln \left( \frac{2V - b}{V - b} \right) \] 6. **Substituting the number of moles**: Since we have 1 mole of gas (\( n = 1 \)): \[ W = RT \ln \left( \frac{2V - b}{V - b} \right) \] ### Final Answer: The work done during the isothermal expansion of the gas is: \[ W = RT \ln \left( \frac{2V - b}{V - b} \right) \]

To solve the problem, we need to calculate the work done during the isothermal expansion of 1 mole of gas from volume \( V \) to \( 2V \) using the given equation of state \( p(V-b) = nRT \). ### Step-by-Step Solution: 1. **Identify the equation of state**: The equation is given as: \[ p(V - b) = nRT ...
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The equation of state of a gas is given as P(V-b)=nRT, where b is constant ,n is the number of moles and R is the universal gas constant .when 2 moles of this gas undergo reversible isothermal expansion from volume V to 2V ,what is work done by the gas ?

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Knowledge Check

  • An ideal gas system undergoes an isothermal process, then the work done during the process is

    A
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    B
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    C
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    D
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    A
    `[ML^(8)T^(-2)] and [L^(3//2)]`
    B
    `[ML^(5)T^(-2)] and [L^(3)]`
    C
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