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A hydrogen atom ia in excited state of ...

A hydrogen atom ia in excited state of principal quantum number `n` . It emits a photon of wavelength `lambda` when it returnesto the ground state. The value of `n` is

A

`sqrt(lambdaR(lambdaR-1))`

B

`sqrt((lambdaR-1)/(lambda))`

C

`sqrt((lambda)/(lambdaR-1))`

D

`sqrt(lambda(R-1))`

Text Solution

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The correct Answer is:
To solve the problem, we need to determine the principal quantum number \( n \) of a hydrogen atom that emits a photon of wavelength \( \lambda \) when it transitions from an excited state to the ground state. ### Step-by-Step Solution: 1. **Understand the Transition**: The hydrogen atom transitions from an excited state with principal quantum number \( n \) to the ground state, which has \( n_1 = 1 \). 2. **Use the Wavelength Formula**: The wavelength of the emitted photon can be described by the formula: \[ \frac{1}{\lambda} = R \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] where \( R \) is the Rydberg constant, \( n_1 \) is the lower energy level (ground state, \( n_1 = 1 \)), and \( n_2 \) is the higher energy level (excited state, \( n_2 = n \)). 3. **Substitute Known Values**: Since \( n_1 = 1 \) and \( n_2 = n \), we can substitute these into the formula: \[ \frac{1}{\lambda} = R \left( 1 - \frac{1}{n^2} \right) \] 4. **Rearranging the Equation**: Rearranging gives us: \[ \frac{1}{\lambda} = R - \frac{R}{n^2} \] This can be rewritten as: \[ \frac{R}{n^2} = R - \frac{1}{\lambda} \] 5. **Isolate \( n^2 \)**: Rearranging further, we find: \[ \frac{1}{n^2} = \frac{R - \frac{1}{\lambda}}{R} \] Taking the common denominator on the right-hand side gives: \[ \frac{1}{n^2} = \frac{\lambda R - 1}{\lambda R} \] 6. **Taking Reciprocals**: Taking the reciprocal of both sides, we get: \[ n^2 = \frac{\lambda R}{\lambda R - 1} \] 7. **Finding \( n \)**: Finally, taking the square root of both sides yields: \[ n = \sqrt{\frac{\lambda R}{\lambda R - 1}} \] ### Conclusion: Thus, the value of \( n \) is: \[ n = \sqrt{\frac{\lambda R}{\lambda R - 1}} \]
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