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Calculate the pH at the equivalence poin...

Calculate the pH at the equivalence point when a solution of 0.1 M `CH_3COOH` is titrated with a solution of 0.1 M NaOH.
`K_a(CH_3COOH)= 1.8 xx 10^(-5)`

Text Solution

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To calculate the pH at the equivalence point when a solution of 0.1 M acetic acid (CH₃COOH) is titrated with a solution of 0.1 M NaOH, we need to follow these steps: ### Step 1: Understand the Reaction At the equivalence point, all the acetic acid (CH₃COOH) has reacted with NaOH to form sodium acetate (CH₃COONa). The reaction can be represented as: \[ \text{CH}_3\text{COOH} + \text{NaOH} \rightarrow \text{CH}_3\text{COONa} + \text{H}_2\text{O} \] ### Step 2: Determine the Concentration of the Conjugate Base At the equivalence point, the concentration of the conjugate base (acetate ion, CH₃COO⁻) will be the same as the initial concentration of acetic acid, since they are in a 1:1 molar ratio. Therefore, the concentration of CH₃COO⁻ will also be 0.1 M. ...
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Calculate the pH at the equivalence point when a solution of 0.01 M CH_3COOH is titrated with a solution of 0.01 M NaOH. pK_a of CH_3COOH is 4.74.

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Knowledge Check

  • Calculate the pH at the equivalence point when a solution of 0.1M acetic acid is titrated with a solu- tion of 0.1M NaOH, K_a for acid =2 xx 10^(-5)-

    A
    5.7
    B
    6.7
    C
    7.7
    D
    8.7
  • Calculate the pH at the equivalence point during the titration of 0.1M, 25 mL CH_(3)COOH with 0.05M NaOH solution. [K_(a)(CH_(3)COOH) = 1.8 xx 10^(-5)]

    A
    `9.63`
    B
    `8.63`
    C
    `10.63`
    D
    `11.63`
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    Calcualte the pH at the equivalence point when a solution of 0.1M acetic is titrated with a solution of 0.1M NaOH.(K_(a)for acid = 1.9xx10^(-5)) .

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