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Vapour Pressure OF Solution and Liquid C...

Vapour Pressure OF Solution and Liquid Composition Curve || Relation between Mole Fraction in Liquid Phase and Vapour Phase || Vapour and Liquid Composition Curve

Answer

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Knowledge Check

  • Vapour pressure of a liquid depends on

    A
    Volume of container
    B
    Amount of liquid
    C
    Surface area of container
    D
    Temperature
  • During phase transformation of vapour into liquid :-

    A
    It absorbs heat
    B
    It releases heat
    C
    Its temp. increases
    D
    Its temp. decreases
  • In non-ideal solutions, at one of the intermediate compositions, the total vapour pressure is highest and the boiling point is lowest. At this point, the composition of the liquid and vapour phase is same. So, if liquid mixture vapourises at this point and vapours are condensed, the condensate contains same composition as present in orginal liquid mixture. It means that at this point liquid behaves like a pure and is called as Azeotropic mixture. Choose the correct answer : Choose the correct statemnent

    A
    Ideal solutions connot be separated into their components by frectional distillation
    B
    For ideal solution, entghalpy of mixing is always greater than zero
    C
    Only non-ideal solution showing positive devialtion cannot be separeated out by fration distillation.
    D
    Non-ideal solution showing both positive and ngative deviation cannot be separated out by fractional distillation.
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    (a) Derive a relationship between relative lowering of vapour pressure and mole fraction of the volatile liquid. (b) (i) Benzoic acid completely dimerises in benzene. What will be vapour pressure of a solution containing 61 g of benzoic acid per 500 g of benzene when the vapour pressure of pure benzene at the temperature of experiment is 66.6 torr ? (ii) What would have been the vapour pressure in the absence of dimerisation ? (iii) Derive a relationship between mole fraction and vapour pressure of a component of an ideal solution in the liquid phase and vapour phase.