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Equivalent mass of C(2)O(4)^(2-) ion in ...

Equivalent mass of `C_(2)O_(4)^(2-)` ion in the reaction,
`C_(2)O_(4)^(2-)to2CO_(2)+2e^(-)`, is

A

11

B

22

C

44

D

88

Text Solution

AI Generated Solution

The correct Answer is:
To find the equivalent mass of the \( C_2O_4^{2-} \) ion in the reaction \[ C_2O_4^{2-} \rightarrow 2CO_2 + 2e^- \] we will follow these steps: ### Step 1: Determine the n-factor The n-factor is defined as the total number of electrons lost or gained in the reaction. In this case, we can see that \( C_2O_4^{2-} \) is losing 2 electrons to form \( 2CO_2 \). Thus, the n-factor for this reaction is 2. ### Step 2: Calculate the molecular mass of \( C_2O_4^{2-} \) To find the molecular mass, we need to sum the atomic masses of all the atoms in the ion: - Carbon (C) has an atomic mass of approximately 12 g/mol. - Oxygen (O) has an atomic mass of approximately 16 g/mol. The molecular mass of \( C_2O_4^{2-} \) is calculated as follows: \[ \text{Molecular mass} = 2 \times (12) + 4 \times (16) \] \[ = 24 + 64 \] \[ = 88 \text{ g/mol} \] ### Step 3: Calculate the equivalent mass The equivalent mass is calculated using the formula: \[ \text{Equivalent mass} = \frac{\text{Molecular mass}}{n \text{-factor}} \] Substituting the values we found: \[ \text{Equivalent mass} = \frac{88 \text{ g/mol}}{2} = 44 \text{ g/equiv} \] ### Conclusion Thus, the equivalent mass of the \( C_2O_4^{2-} \) ion is **44 g/equiv**. ---
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Knowledge Check

  • [Co(C_(2)O_(4))_(3)]^(3-) is a

    A
    `C_(2)O_(4)^(2-)` is strong field ligand hence causes pairing of electrons
    B
    `C_(2)O_(4)^(2-)` is a bidentate ligand hence causes pairing of electrons
    C
    `Co^(3+)` is a strong central atom hence in all complexes of `Co^(3+)` electrons are paired
    D
    `C_(2)O_(4)^(2-)` is a strong field ligand hence causes splitting of d-orbitals .
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