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Electrolysis of KCl. MgCl2 . 6H2O gives:...

Electrolysis of `KCl. MgCl_2 . 6H_2O` gives:
potassium only
magnesium only
magnesium and chlorine
potassium and magnesium.

A

potassium only

B

magnesium only

C

magnesium and chlorine

D

potassium and magnesium.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the electrolysis of KCl·MgCl₂·6H₂O, we can follow these steps: ### Step 1: Understand the Components The compound KCl·MgCl₂·6H₂O consists of potassium chloride (KCl) and magnesium chloride (MgCl₂) in a hydrated form. During electrolysis, these compounds will dissociate into their respective ions. ### Step 2: Identify the Ions When KCl and MgCl₂ dissolve in water, they dissociate into: - K⁺ (potassium ions) - Cl⁻ (chloride ions) - Mg²⁺ (magnesium ions) ### Step 3: Analyze the Electrolysis Process During electrolysis, the following reactions can occur: - At the cathode (reduction), cations (K⁺ and Mg²⁺) will gain electrons. - At the anode (oxidation), anions (Cl⁻) will lose electrons. ### Step 4: Compare Reduction Potentials The reduction potentials of the ions are crucial in determining which will be reduced: - The standard reduction potential for K⁺ + e⁻ → K is approximately -2.93 V. - The standard reduction potential for Mg²⁺ + 2e⁻ → Mg is approximately -2.37 V. Since the reduction potential of Mg²⁺ is higher (less negative) than that of K⁺, magnesium ions will be preferentially reduced at the cathode. ### Step 5: Determine the Products - At the cathode, magnesium (Mg) will be produced from Mg²⁺ ions. - At the anode, chloride ions (Cl⁻) will be oxidized to produce chlorine gas (Cl₂). ### Conclusion Thus, the electrolysis of KCl·MgCl₂·6H₂O will yield magnesium and chlorine gas as the products. ### Final Answer The correct option is: **Magnesium and Chlorine.** ---

To solve the question regarding the electrolysis of KCl·MgCl₂·6H₂O, we can follow these steps: ### Step 1: Understand the Components The compound KCl·MgCl₂·6H₂O consists of potassium chloride (KCl) and magnesium chloride (MgCl₂) in a hydrated form. During electrolysis, these compounds will dissociate into their respective ions. ### Step 2: Identify the Ions When KCl and MgCl₂ dissolve in water, they dissociate into: - K⁺ (potassium ions) ...
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  • Mixture of MgCl_2 and Mgo is called

    A
    Portland cement
    B
    Sorel's cement
    C
    double salt
    D
    none of these
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