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Which of the following compounds will ex...

Which of the following compounds will exhibit cis-trans (geometrical) isomerism?

A

But-2-ene

B

But-2-yne

C

Butan-2-ol

D

But-1-ene

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given compounds will exhibit cis-trans (geometrical) isomerism, we need to analyze the structures of the compounds and check if they meet the necessary conditions for geometrical isomerism. ### Step-by-Step Solution: 1. **Understanding Geometrical Isomerism**: - Geometrical isomerism, also known as cis-trans isomerism, occurs in alkenes where there is restricted rotation around a double bond. - For a compound to exhibit cis-trans isomerism, it must have two different groups attached to each carbon of the double bond. 2. **Identifying the Compounds**: - Let's analyze the provided options. We will focus on alkenes since only they can exhibit cis-trans isomerism. 3. **Analyzing But-2-ene**: - Structure: CH3-CH=CH-CH3 - In but-2-ene, the double bond is between the second and third carbon atoms. - Groups attached to the double bond are: - C2: CH3 (R1) and H (R2) - C3: H (R3) and CH3 (R4) - Since R1 (CH3) is not equal to R2 (H) and R3 (H) is not equal to R4 (CH3), but-2-ene can exhibit cis-trans isomerism. 4. **Analyzing Butane**: - Butane is a straight-chain alkane (C4H10) and does not have a double bond. - Since it is not an alkene, butane cannot exhibit geometrical isomerism. 5. **Analyzing Bute-1-ene**: - Structure: CH2=CH-CH2-CH3 - In bute-1-ene, the double bond is between the first and second carbon atoms. - Groups attached to the double bond are: - C1: H (R1) and CH2 (R2) - C2: CH2 (R3) and CH3 (R4) - Here, R1 (H) is equal to R2 (H), which means bute-1-ene cannot exhibit geometrical isomerism. 6. **Conclusion**: - The only compound that exhibits cis-trans isomerism among the options is but-2-ene. ### Final Answer: The compound that will exhibit cis-trans (geometrical) isomerism is **but-2-ene**.
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Knowledge Check

  • Which of the following compounds will show cis-trans isomerism?

    A
    `(CH_(3))_(2)C=CHC_(2)H_(5)`
    B
    `H_(2)C=C Cl_(2)`
    C
    `CH_(3)HC=C ClCH_(3)`
    D
    `HClC=CH_(2)`
  • Which of the following would exhibit cis-trans isomerism?

    A
    `CH_(3)CH_(2)CH=CH_(2)`
    B
    `ClCH=CHCl`
    C
    `ClCH=C Cl_(2)`
    D
    `CH_(2)=CH-COOH`
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