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Assertion : The carbon-carbon bond lengt...

Assertion : The carbon-carbon bond length in benzene lies between the bond lengths of C-C and C=C bonds found in other molecules.
Reason: Benzene exhibits the phenomenon of resonance

A

If both Assertion and Reason are CORRECT and Reason is the CORRECT explanation of the Assertion.

B

If both Assertion and Reason are CORRECT but Reason is not the CORRECT explanation of the Assertion.

C

I Assertion is CORRECT but Reason is INCORRECT.

D

If Assertion is INCORRECT but Reason is CORRECT.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we will analyze both the assertion and the reason provided. ### Step 1: Understand the Assertion The assertion states that the carbon-carbon bond length in benzene lies between the bond lengths of carbon-carbon single bonds and carbon-carbon double bonds found in other molecules. - **Bond Lengths**: - The bond length of a carbon-carbon single bond (C-C) is approximately 1.54 Å. - The bond length of a carbon-carbon double bond (C=C) is approximately 1.34 Å. - The bond length in benzene (C6H6) is measured to be around 1.40 Å. ### Step 2: Analyze the Bond Length in Benzene From the bond lengths mentioned: - The bond length of benzene (1.40 Å) is indeed between the bond lengths of C-C (1.54 Å) and C=C (1.34 Å). Thus, the assertion is **correct**. ### Step 3: Understand the Reason The reason provided states that benzene exhibits the phenomenon of resonance. - **Resonance in Benzene**: - Benzene can be represented by multiple resonance structures (canonical forms), which show the delocalization of electrons across the carbon atoms. - This delocalization means that the bonds in benzene are not purely single or double but have characteristics of both. ### Step 4: Connect the Reason to the Assertion Due to resonance: - The carbon-carbon bonds in benzene have a partial double bond character and a partial single bond character. - This results in bond lengths that are intermediate between a single bond and a double bond. Thus, the reason is also **correct** and provides a valid explanation for the assertion. ### Conclusion Both the assertion and the reason are correct, and the reason correctly explains the assertion. ### Final Answer The correct option is: **A** (Both assertion and reason are correct, and the reason is the correct explanation of the assertion). ---
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Knowledge Check

  • What is the carbon-carbon bond length in benzene?

    A
    1.20 Å and 1.31 Å
    B
    1.39 Å
    C
    1.39 Å and 1.20 Å
    D
    1.20 Å
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