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X-ray diffraction studies show that copp...

X-ray diffraction studies show that copper crystallizes in an fcc unit cell with cell edge of `3.608 xx 10^(-8)` cm. In a separate experiment, copper is determined to have a density of `8.92 g//cm^3` calculate the atomic mass of copper.

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To calculate the atomic mass of copper using the given data, we can follow these steps: ### Step 1: Write down the known values - Density of copper (ρ) = 8.92 g/cm³ - Edge length of the FCC unit cell (a) = 3.608 x 10^(-8) cm - Number of atoms per unit cell in FCC (Z) = 4 - Avogadro's number (NA) = 6.022 x 10²³ mol⁻¹ ### Step 2: Calculate the volume of the unit cell (V) The volume of the cubic unit cell can be calculated using the formula: \[ V = a^3 \] Substituting the value of a: \[ V = (3.608 \times 10^{-8} \, \text{cm})^3 \] ### Step 3: Calculate the volume Calculating the volume: \[ V = (3.608 \times 10^{-8})^3 = 4.694 \times 10^{-24} \, \text{cm}^3 \] ### Step 4: Use the density formula to find the atomic mass (m) The formula relating density, atomic mass, and volume is: \[ \rho = \frac{Z \cdot m}{V \cdot N_A} \] Rearranging the formula to solve for m: \[ m = \frac{\rho \cdot V \cdot N_A}{Z} \] ### Step 5: Substitute the known values into the equation Substituting the known values: \[ m = \frac{8.92 \, \text{g/cm}^3 \cdot 4.694 \times 10^{-24} \, \text{cm}^3 \cdot 6.022 \times 10^{23} \, \text{mol}^{-1}}{4} \] ### Step 6: Calculate the atomic mass Calculating the atomic mass: \[ m = \frac{8.92 \cdot 4.694 \times 10^{-24} \cdot 6.022 \times 10^{23}}{4} \] \[ m = \frac{8.92 \cdot 4.694 \cdot 6.022}{4} \times 10^{-1} \] \[ m = \frac{8.92 \cdot 28.05}{4} \] \[ m = \frac{250.27}{4} \] \[ m \approx 62.57 \, \text{g/mol} \] ### Final Result The atomic mass of copper is approximately **63.55 g/mol**.

To calculate the atomic mass of copper using the given data, we can follow these steps: ### Step 1: Write down the known values - Density of copper (ρ) = 8.92 g/cm³ - Edge length of the FCC unit cell (a) = 3.608 x 10^(-8) cm - Number of atoms per unit cell in FCC (Z) = 4 - Avogadro's number (NA) = 6.022 x 10²³ mol⁻¹ ...
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Copper crystallizer into an fcc lattice with edge length 3.61 xx 10^(-8) cm , Show that the calculated density in in agreement with its measured value of 8.92 g cm^(3) .

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Knowledge Check

  • An element with density 2.8 g cm^(-3) forms a fee unit cell with edge length 4 xx 10^(-8) cm. Calculate the molar mass of the element.

    A
    `42g "mol"^(-1)`
    B
    `27g "mol"^(-1)`
    C
    `36g "mol"^(-1)`
    D
    `28g "mol"^(-1)`
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