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Why is white phosphorus stored under wat...

Why is white phosphorus stored under water?

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Due to its low ignition temperature (303 K), white phosphorus on exposure to air, spontaneously catches fire. Therefore, to protect it from air, white phosphorus is stored under water.
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When white phosphorous is stored for longer period it appears yellow due to :

Knowledge Check

  • White phosphorus reacts with chlorine and the product hydrolyses in the presence of water. Calcualte the mass of HCl obtained by the hydrolysis of the product formed by the reaction of 62 g of white phosphorus with chlorine in the presence of water.

    A
    200 g
    B
    400 g
    C
    219 g
    D
    100 g
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    White phosphorus (P_4) has

    (a)What happens when white phosphorus is heated with concentrated NaOH solution in an inert atmosphere of CO_(2) ? (b)Draw the structure of white phosphorus and red phosphorus. Which one of these two types of phosphorus, is more reactive and why ?

    White phosphorus reacts with chlorine and the product hydrolyses in the presence of water. Calcualte the mass of HCl obtained by the hydrolysis of the product formed by the reaction of 62 g of white phosphorus with chlorine in the presence of water.

    Explain the high reactivity of white phosphorus as compared to red phosphorus.

    What happens when white phosphorus is boiled with a strong solution of NaOH in moist atmosphere ?

    What happens when white phosphorus is heated with conc. NaOH solution in an inert atmosphere of CO_(2) ?

    Why is red phosphorus less reactive than white phosphorus ?