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Conversion of nitrobenzene to aniline is...

Conversion of nitrobenzene to aniline is carried out in

A

neutral medium

B

acidic medium

C

alkaline medium

D

none

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The correct Answer is:
To convert nitrobenzene to aniline, we need to follow a series of steps that involve the reduction of the nitro group (-NO2) to an amino group (-NH2). The process is typically carried out in an acidic medium. Here’s a step-by-step breakdown of the conversion: ### Step 1: Understanding Nitrobenzene - Nitrobenzene is an aromatic compound with the formula C6H5NO2, where the nitro group (-NO2) is attached to a benzene ring. ### Step 2: Choosing the Medium - The conversion of nitrobenzene to aniline can occur in different mediums: neutral, acidic, or alkaline. However, the most effective medium for this reduction is acidic. ### Step 3: Reaction in Acidic Medium - In an acidic medium, nitrobenzene undergoes reduction. A common method involves using tin (Sn) and hydrochloric acid (HCl). The reaction can be summarized as follows: - Nitrobenzene (C6H5NO2) is treated with Sn and HCl. - This leads to the formation of nitrosobenzene (C6H5NO) as an intermediate. ### Step 4: Formation of Aniline - The nitrosobenzene can further react in the presence of additional hydrogen (H2) to yield phenylhydroxylamine (C6H5NHOH). - Finally, phenylhydroxylamine can be reduced further to form aniline (C6H5NH2) by adding more hydrogen. ### Step 5: Conclusion - Thus, the conversion of nitrobenzene to aniline is effectively carried out in an acidic medium. Therefore, the correct answer is **acidic medium**. ### Final Answer: **The conversion of nitrobenzene to aniline is carried out in acidic medium.** ---

To convert nitrobenzene to aniline, we need to follow a series of steps that involve the reduction of the nitro group (-NO2) to an amino group (-NH2). The process is typically carried out in an acidic medium. Here’s a step-by-step breakdown of the conversion: ### Step 1: Understanding Nitrobenzene - Nitrobenzene is an aromatic compound with the formula C6H5NO2, where the nitro group (-NO2) is attached to a benzene ring. ### Step 2: Choosing the Medium - The conversion of nitrobenzene to aniline can occur in different mediums: neutral, acidic, or alkaline. However, the most effective medium for this reduction is acidic. ...
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ICSE-ORGANIC COMPOUNDS CONTAINING NITROGEN-EXERCISE (PART-I OBJECTIVE QUESTIONS)
  1. An isonitrile on reduction gives

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  2. Hydrolysis of benzonitrile gives

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  3. Conversion of nitrobenzene to aniline is carried out in

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  4. Towards electrophilic substitution, the most reactive will be

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  5. Acetanilide is prepared by the reaction of acetyl chloride on

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  6. Which of the following gives carbylamine reaction?

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  7. The compound obtained by heating a mixture of a primary amine and chlo...

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  8. which of the following reactions will not give a primary amine ?

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  9. Gabrial synthesis is used for the preparation of

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  10. Nitrosoamines (R2 N-N=O) are insoluble in water. On heating them with ...

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  11. Which of the following is a 3^@ amine?

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  12. The correct IUPAC name for CH2=CHCH2NHCH3 is

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  13. Amongst the following, the strongest base in aqueous medium is .

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  14. Which of the following is the weakest Bronsted base?

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  15. Benzyl amine may be alkylated as shown in the following equation : ...

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  16. Which of the following reagents would not be a good choice for reducin...

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  17. In order to prepare a 1^(@) amine from an alkyl halide with simultaneo...

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  18. The souce of nitrogen in Gabriel synthesis of amines is

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  19. Amongst the given set of reactants the most appropriate for preparing ...

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  20. The best reagent for converting 2-phenylpropanamide into 2-phenylpropa...

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