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A given metal crystalline out with a cu...

A given metal crystalline out with a cubic structure having edge length of `361` pm .if there are four metal atoms in one unit cell, what is the radius of metal atom?

A

40 pm

B

127 pm

C

80 pm

D

108 pm

Text Solution

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The correct Answer is:
To find the radius of a metal atom in a cubic crystal structure with a given edge length and number of atoms in the unit cell, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Type of Cubic Structure:** - Given that there are 4 metal atoms in one unit cell, we can conclude that the structure is Face-Centered Cubic (FCC). In FCC, there are 8 corner atoms (1/8 contribution each) and 6 face atoms (1/2 contribution each), which totals to 4 atoms: \[ \text{Total atoms} = \left(8 \times \frac{1}{8}\right) + \left(6 \times \frac{1}{2}\right) = 1 + 3 = 4 \] 2. **Given Data:** - Edge length (A) = 361 pm (picometers) 3. **Relate Edge Length to Atomic Radius:** - In an FCC structure, the relationship between the edge length (A) and the atomic radius (R) is given by: \[ A = 2\sqrt{2}R \] - This relationship arises from the geometry of the FCC structure, where the diagonal of the face of the cube equals four atomic radii (2R). 4. **Rearranging the Formula:** - To find the radius (R), we rearrange the formula: \[ R = \frac{A}{2\sqrt{2}} \] 5. **Substituting the Given Edge Length:** - Now substitute the value of A into the formula: \[ R = \frac{361 \text{ pm}}{2\sqrt{2}} \] 6. **Calculating the Radius:** - First, calculate \(2\sqrt{2}\): \[ 2\sqrt{2} \approx 2 \times 1.414 = 2.828 \] - Now divide: \[ R \approx \frac{361}{2.828} \approx 127.0 \text{ pm} \] 7. **Final Answer:** - The radius of the metal atom is approximately 127 pm. ### Summary: The radius of the metal atom in the given FCC structure with an edge length of 361 pm is approximately **127 pm**.

To find the radius of a metal atom in a cubic crystal structure with a given edge length and number of atoms in the unit cell, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Type of Cubic Structure:** - Given that there are 4 metal atoms in one unit cell, we can conclude that the structure is Face-Centered Cubic (FCC). In FCC, there are 8 corner atoms (1/8 contribution each) and 6 face atoms (1/2 contribution each), which totals to 4 atoms: \[ \text{Total atoms} = \left(8 \times \frac{1}{8}\right) + \left(6 \times \frac{1}{2}\right) = 1 + 3 = 4 ...
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Knowledge Check

  • Copper crystallises in fcc with a unit cell length of 361 pm. What is the radius of copper atom?

    A
    157 pm
    B
    181 pm
    C
    127 pm
    D
    108 pm
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