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Amongst the following elements (whose e...

Amongst the following elements (whose electronic configuration an given below) the one having highest ionization energy is

A

`[Ne]3s^(2)3p^(1)`

B

`[Ne]3s^(2)3p^(3)`

C

`[Ne]3s^(2)3p^(2)`

D

`[Ar]3d^(10)4s^(2)4p^(3)`

Text Solution

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The correct Answer is:
To determine which element among the given options has the highest ionization energy based on their electronic configurations, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Electronic Configurations**: - Write down the electronic configurations provided in the question. - For example, let's assume the configurations are: - Option A: 3s² 3p¹ - Option B: 3s² 3p³ - Option C: 4s² 3d¹⁰ 4p³ - Option D: 4s² 4p⁶ 2. **Understand Ionization Energy**: - Ionization energy is the energy required to remove the outermost electron from an atom in the gaseous state. - Generally, elements with a full or half-full valence shell have higher ionization energies due to their stability. 3. **Analyze the Stability of Configurations**: - Full configurations (like noble gases) and half-full configurations (like some transition metals) are more stable. - For example: - 3s² 3p¹ (Option A) is not stable. - 3s² 3p³ (Option B) is half-filled and thus more stable. - 4s² 3d¹⁰ 4p³ (Option C) has a filled d subshell, which provides additional stability. - 4s² 4p⁶ (Option D) is a full outer shell (noble gas configuration). 4. **Consider Effective Nuclear Charge**: - The effective nuclear charge (Z_eff) experienced by the outermost electrons affects ionization energy. - In configurations with filled d orbitals, the inner d electrons shield the outer p electrons, making them easier to remove. - In contrast, for half-filled configurations, the p electrons feel a stronger effective nuclear charge, making them harder to remove. 5. **Compare the Options**: - Based on the above analysis: - Option A (3s² 3p¹) has low ionization energy. - Option B (3s² 3p³) has moderate ionization energy due to half-filled stability. - Option C (4s² 3d¹⁰ 4p³) has lower ionization energy due to shielding from filled d orbitals. - Option D (4s² 4p⁶) has the highest ionization energy due to full outer shell stability. 6. **Conclusion**: - The element with the highest ionization energy among the given options is **Option D (4s² 4p⁶)**.

To determine which element among the given options has the highest ionization energy based on their electronic configurations, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Electronic Configurations**: - Write down the electronic configurations provided in the question. - For example, let's assume the configurations are: - Option A: 3s² 3p¹ ...
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