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[Co(H2O)6]^(3+) is diamagnetic wheras [C...

`[Co(H_2O)_6]^(3+)` is diamagnetic wheras `[Co(F_6)]^(3-)]` is paramagnetic. Explain.

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[Co(NH_(3))_(6)]^(3+) & [CoF_(6)]^(3-) both are complexes of Co(III), but [Co(NH_(3))_(6)]^(3+) is diamagnetic while [Co(F_(6)]^(3-) is paramagnetic with mu=4.90 BM . Explain.

[Co(NH_(3))_(6)]^(3+) is diamagnetic while [CoF_(6)]^(3-) is_____ .

Knowledge Check

  • Explain the following: (i) [CoF_(6)]^(3-) is paramgnetic but [Co(CN)_(6)]^(3-) is diamagnetic .

    A
    paramagnetic and undergoes `sp^(3) d^(2)` hybridisation
    B
    diamagnetic and undergoes `d^(2) sp^(3)` hybridisation
    C
    paramagnetic and undergoes `sp^(3) d` hybridisation
    D
    diamagnetic and undergoes `sp^(3)` hybridisation .

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    [Cr(NH_3)_6]^(3+) is paramagnetic while [Ni(CN)_4]^(2-) is diamagnetic. Explain why?

    [Fe(H_2O)_6]^(3+) is strongly paramagnetic whereas [Fe(CN)_6]^(3-) is weakly paramagnetic. Explain.

    [Fe(H_2O)_6]^(3+) is strongly paramagnetic whereas [Fe(CN)_6]^(3-) is weakly paramagnetic. Explain.

    [Co(H_(2)O)_(6)]^(3+) complex is

    How would you account for the following : [Fe(CN)_6]^(3-) is weakly paramagnetic while [Fe(CN)_6]^(4-) is diamagnetic

    In the following questions , a statement of assertion (A) is followed by a statement of reason (R). A: [Co(NH_3)_6]^(3+) is a diamagnetic complex. R: [Co(NH_3)_6]^(3+) has octahedral shape.

    Explain the following: (i) All the octahedral complexes of Ni^(2+) must be outer orbital complexes. (ii) [CoF_(6)]^(3-) is paramgnetic but [Co(CN)_(6)]^(3-) is diamagnetic .

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