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Which out of the following substituent i...

Which out of the following substituent increases the acid strength of phenol.
- CN or -`NH_(2)`

Text Solution

AI Generated Solution

To determine which substituent increases the acid strength of phenol between -CN (cyanide) and -NH2 (amino), we can follow these steps: ### Step 1: Understand the Structure of Phenol Phenol is a benzene ring with a hydroxyl (-OH) group attached. The acidity of phenol is influenced by substituents attached to the benzene ring. ### Step 2: Identify the Effects of Substituents - **-CN (Cyanide)**: This group is an electron-withdrawing group due to its -I (inductive) and -R (resonance) effects. It pulls electron density away from the benzene ring and the -OH group. - **-NH2 (Amino)**: This group is an electron-donating group because it has a lone pair of electrons that can be donated to the benzene ring through resonance (+R effect). However, it also has a -I effect, but it is weaker compared to its +R effect. ...
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Knowledge Check

  • Which of the following substituents will decrease the acidic strength of phenol?

    A
    `-NO_2`
    B
    `-CN`
    C
    `-CH_3`
    D
    `-CHO`
  • Which of the following substance will increase the acidity of phenol ?

    A
    Dil. `H_2SO_4`
    B
    Dil. HCl
    C
    conc. `H_2SO_4`
    D
    conc. `CH_3COOH`
  • Which of the following represents the correct order of acidic strength ?

    A
    HOCI lt HOBr lt HOI
    B
    HOCI lt HOI lt HOBr
    C
    HOBr lt HOI lt HOCI
    D
    HOI lt HOBr lt HOCI
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