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Metals have few electrons in their valen...

Metals have few electrons in their valence shell while non-metals generally have more electrons in their valence shell. Metallic character is closely related to atomic radius and ionisation enthalpy. Metallic character increases from top to bottom in a group and decreases from let to right in a period of periodic table. metallic character is inversely related to electronegativity of element.
Q. The electronegativity of the following elements increase in the order:

A

C, N, Si, P

B

N, Si, C, P

C

Si, P, C, N

D

P, SI, N, C

Text Solution

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The correct Answer is:
To determine the increasing order of electronegativity for the given elements (carbon, silicon, germanium, tin, lead, nitrogen, phosphorus, arsenic, antimony, bismuth), we can follow these steps: ### Step-by-Step Solution: 1. **Understanding Electronegativity**: Electronegativity is defined as the tendency of an atom to attract electrons towards itself in a chemical bond. It generally increases across a period and decreases down a group in the periodic table. 2. **Identify the Groups**: The elements can be categorized into two groups: - Group 14: Carbon (C), Silicon (Si), Germanium (Ge), Tin (Sn), Lead (Pb) - Group 15: Nitrogen (N), Phosphorus (P), Arsenic (As), Antimony (Sb), Bismuth (Bi) 3. **Trends in Electronegativity**: - **Across a Period**: Electronegativity increases from left to right due to increasing nuclear charge and decreasing atomic radius. - **Down a Group**: Electronegativity decreases due to increasing atomic size and shielding effect. 4. **Comparing Group 14 Elements**: - **Electronegativity Order**: C > Si > Ge > Sn > Pb - Carbon has the highest electronegativity in this group, while lead has the lowest. 5. **Comparing Group 15 Elements**: - **Electronegativity Order**: N > P > As > Sb > Bi - Nitrogen has the highest electronegativity in this group, while bismuth has the lowest. 6. **Combining the Results**: - From Group 14: C > Si > Ge > Sn > Pb - From Group 15: N > P > As > Sb > Bi - The overall order of electronegativity from highest to lowest is: N > C > P > Si > Ge > As > Sn > Bi > Pb. 7. **Finalizing the Increasing Order**: - To express the increasing order of electronegativity, we write it from the least electronegative to the most electronegative: - **Increasing Order**: Pb < Bi < Sb < As < Sn < Ge < Si < P < C < N ### Final Answer: The electronegativity of the following elements increases in the order: Pb < Bi < Sb < As < Sn < Ge < Si < P < C < N.
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