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Pb(3)O(4)+HCl (dil.)overset(warm) to PbC...

`Pb_(3)O_(4)+HCl (dil.)overset(warm) to PbCl_(2)darr+Cl_(2)+H_(2)O`

A

For disproportionation reaction.

B

For comproportionation reaction.

C

For either intermolecular redox reaction or displacement reaction

D

For either thermal combination redox reaction or thermal decomposition redox reaction.

Text Solution

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The correct Answer is:
To analyze the reaction \( \text{Pb}_3\text{O}_4 + \text{HCl (dil.)} \overset{\text{warm}}{\rightarrow} \text{PbCl}_2 + \text{Cl}_2 + \text{H}_2\text{O} \), we will determine the oxidation states of the elements involved and identify the type of reaction. ### Step 1: Determine Oxidation States 1. **Lead in \( \text{Pb}_3\text{O}_4 \)**: Let the oxidation state of lead be \( x \). - The equation for the oxidation states is: \[ 3x + 4(-2) = 0 \] \[ 3x - 8 = 0 \implies 3x = 8 \implies x = \frac{8}{3} \] - Therefore, the oxidation state of lead in \( \text{Pb}_3\text{O}_4 \) is \( +\frac{8}{3} \). 2. **Oxygen in \( \text{Pb}_3\text{O}_4 \)**: The oxidation state of oxygen is \( -2 \). 3. **Hydrogen in \( \text{HCl} \)**: The oxidation state of hydrogen is \( +1 \). 4. **Chlorine in \( \text{HCl} \)**: The oxidation state of chlorine is \( -1 \). 5. **Lead in \( \text{PbCl}_2 \)**: The oxidation state of lead here is \( +2 \). 6. **Chlorine in \( \text{Cl}_2 \)**: The oxidation state of chlorine is \( 0 \). 7. **Oxygen in \( \text{H}_2\text{O} \)**: The oxidation state of oxygen is \( -2 \). ### Step 2: Analyze Changes in Oxidation States - **Lead**: Changes from \( +\frac{8}{3} \) to \( +2 \) (Reduction). - **Chlorine**: Changes from \( -1 \) in \( \text{HCl} \) to \( 0 \) in \( \text{Cl}_2 \) (Oxidation). ### Step 3: Identify the Type of Reaction - Since one species (lead) is being reduced (gaining electrons) and another species (chlorine) is being oxidized (losing electrons), this reaction is classified as a redox reaction. - Specifically, since the oxidation and reduction are occurring between two different species, this is an **intermolecular redox reaction**. ### Conclusion The type of reaction is an **intermolecular redox reaction**.
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