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Correct order of bond angle in given spe...

Correct order of bond angle in given species is:

A

`SiO_(4)^(4-) gt PCl_(3) gt NCl_(3) gt SbH_(3) gt H_(2) Te`

B

`SiO_(4)^(4-) gt NCl_(3) gt PCl_(3) gt SbH_(3) gt H_(2)Te`

C

`SiO_(4)^(4-) gt H_(2) Te gt SbH_(3) gt PCl_(3) gt NCl_(3)`

D

`NCl_(3) gt PCl_(3) gt SiO_(4)^(4-) gt SbH_(3) gt H_(2)Te`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct order of bond angles in the given species (SiO4^4-, BCl3, NCl3, SbH3, and H2Te), we will analyze each compound step by step based on their molecular geometry and the presence of lone pairs. ### Step 1: Analyze SiO4^4- - **Geometry**: SiO4^4- has a tetrahedral geometry. - **Bond Angle**: The bond angle in a perfect tetrahedral structure is approximately 109.5°. ### Step 2: Analyze BCl3 - **Geometry**: BCl3 has a trigonal planar geometry. - **Bond Angle**: The bond angle in a trigonal planar structure is approximately 120°. ### Step 3: Analyze NCl3 - **Geometry**: NCl3 has a trigonal pyramidal geometry due to the presence of one lone pair on nitrogen. - **Bond Angle**: The bond angle is less than 109.5° due to the repulsion from the lone pair, typically around 107°. ### Step 4: Analyze SbH3 - **Geometry**: SbH3 also has a trigonal pyramidal geometry with one lone pair on antimony. - **Bond Angle**: Similar to NCl3, the bond angle is less than 109.5°, typically around 91.5°. ### Step 5: Analyze H2Te - **Geometry**: H2Te has a bent shape due to two lone pairs on tellurium. - **Bond Angle**: The bond angle is significantly smaller than 109.5°, typically around 104.5°. ### Summary of Bond Angles 1. **SiO4^4-**: 109.5° 2. **BCl3**: 120° 3. **NCl3**: ~107° 4. **SbH3**: ~91.5° 5. **H2Te**: ~104.5° ### Correct Order of Bond Angles From the analysis, we can summarize the bond angles in descending order: - **BCl3** (120°) > **SiO4^4-** (109.5°) > **NCl3** (~107°) > **H2Te** (~104.5°) > **SbH3** (~91.5°) ### Final Order Thus, the correct order of bond angles in the given species is: **BCl3 > SiO4^4- > NCl3 > H2Te > SbH3**

To determine the correct order of bond angles in the given species (SiO4^4-, BCl3, NCl3, SbH3, and H2Te), we will analyze each compound step by step based on their molecular geometry and the presence of lone pairs. ### Step 1: Analyze SiO4^4- - **Geometry**: SiO4^4- has a tetrahedral geometry. - **Bond Angle**: The bond angle in a perfect tetrahedral structure is approximately 109.5°. ### Step 2: Analyze BCl3 - **Geometry**: BCl3 has a trigonal planar geometry. ...
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