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Species having X-O-H linkage (X=non-meta...

Species having X-O-H linkage (X=non-metal with positive oxidation state) are called oxy acids and parent acid of a non-metal may exist in two form (a)-ic form of parent oxy acid (b)-us form parent oxy acid.
Q. X-O-X bond (where X=central atom) is not present in species.

A

`Cl_(2)O_(7)`

B

`H_(2)N_(2)O_(7)`

C

`N_(2)O_(5)`

D

`H_(2)S_(2)O_(7)`

Text Solution

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The correct Answer is:
To solve the question regarding the presence of the X-O-X bond in the given species, we will analyze each compound step by step. ### Step 1: Understanding the Compounds We have four species to analyze: 1. Cl2O7 2. H2N2O7 3. N2O5 4. H2S2O7 ### Step 2: Analyzing Cl2O7 - **Structure**: Cl2O7 (Dichlorine heptoxide) consists of two chlorine atoms and seven oxygen atoms. - **Bonding**: The structure features a bridging oxygen atom between the two chlorine atoms, resulting in a Cl-O-Cl bond. - **Conclusion**: Cl2O7 has an X-O-X bond (Cl-O-Cl). ### Step 3: Analyzing H2N2O7 - **Structure**: H2N2O7 (Dinitramic acid) is derived from the combination of HNO3 and HNO4. - **Bonding**: The structure does not contain an N-O-N bond; instead, it features nitrogen atoms bonded to oxygen atoms without forming a direct N-O-N linkage. - **Conclusion**: H2N2O7 does not have an X-O-X bond. ### Step 4: Analyzing N2O5 - **Structure**: N2O5 (Dinitrogen pentoxide) consists of two nitrogen atoms and five oxygen atoms. - **Bonding**: The nitrogen atoms form bonds with oxygen, and there is a bridging structure that leads to an N-O-N bond. - **Conclusion**: N2O5 has an X-O-X bond (N-O-N). ### Step 5: Analyzing H2S2O7 - **Structure**: H2S2O7 (Pyrosulfuric acid) includes two sulfur atoms and seven oxygen atoms. - **Bonding**: The sulfur atoms are connected by an S-O-S bond, indicating a bridging structure. - **Conclusion**: H2S2O7 has an X-O-X bond (S-O-S). ### Final Conclusion From the analysis: - Cl2O7 has an X-O-X bond. - H2N2O7 does not have an X-O-X bond. - N2O5 has an X-O-X bond. - H2S2O7 has an X-O-X bond. Thus, the species that does not have the X-O-X bond is **H2N2O7**.
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