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Which of the following statements is inc...

Which of the following statements is incorrect for `PCl_(5)` ?

A

Its three P-Cl bond lengths are equal

B

It involves `sp^(3)` d hybridization

C

It has an regular geometry

D

Its shpae is trigonal bipyramidal

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AI Generated Solution

The correct Answer is:
To determine which statement is incorrect for \( PCl_5 \), we will analyze the properties and characteristics of the molecule step by step. ### Step 1: Determine the Valence Electrons Phosphorus (P) has 5 valence electrons, and each chlorine (Cl) atom has 7 valence electrons. Since there are 5 chlorine atoms, the total number of valence electrons in \( PCl_5 \) is: \[ \text{Total valence electrons} = 5 + (5 \times 7) = 5 + 35 = 40 \text{ electrons} \] ### Step 2: Bond Pair and Lone Pair Calculation In \( PCl_5 \), phosphorus forms five bonds with the five chlorine atoms. Therefore: - Bond pairs = 5 - Lone pairs = 0 ### Step 3: Hybridization Hybridization can be determined using the formula: \[ \text{Hybridization} = \text{Number of bond pairs} + \text{Number of lone pairs} \] Thus, the hybridization of \( PCl_5 \) is: \[ \text{Hybridization} = 5 + 0 = 5 \quad \Rightarrow \quad \text{sp}^3\text{d} \] ### Step 4: Molecular Geometry The geometry of \( PCl_5 \) can be described as trigonal bipyramidal. In this structure: - There are three chlorine atoms in the equatorial plane forming a triangle. - Two chlorine atoms are positioned axially, one above and one below the equatorial plane. ### Step 5: Analyze the Statements Now we need to evaluate the statements provided regarding \( PCl_5 \): 1. **Statement 1**: The hybridization of \( PCl_5 \) is sp³d. (Correct) 2. **Statement 2**: The molecular shape is trigonal bipyramidal. (Correct) 3. **Statement 3**: The geometry is regular. (Incorrect) 4. **Statement 4**: The bond lengths are equal in the equatorial plane. (Correct) ### Conclusion The incorrect statement regarding \( PCl_5 \) is: **Statement 3**: The geometry is regular.
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VK JAISWAL ENGLISH-CHEMICAL BONDING (BASIC)-SUBJECTIVE PROBLEMS
  1. Which of the following statements is incorrect for PCl(5) ?

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  2. Consider following compounds A to E : (A) XeF(n) " " (B) XeF((n+1)...

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  3. Consider the following five group (According to modern periodic table)...

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  4. Consider the following species and find out total number of species wh...

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  5. Consider the following table regarding interhalogen compounds, XY(n) (...

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  6. What is covalency of chlorine atom in second excited state ?

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  7. Sum of sigma and pi bonds in NH(4)^(+) cation is ..

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  8. Calculate the value of X-Y, for XeOF(4). (X=Number of sigma bond pair ...

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  9. The molecule ABn is planar with six pairs of electrons around A in the...

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  10. Calculate value of (X+Y+Z)/(10), here X is O-N-O bond angle in NO(3)^(...

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  11. Calculate x+y+z for H(3)PO(3) acid, where x is no. of lone pairs, y is...

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  12. How many right angle, bond angles are present in TeF(5)^(-) molecular ...

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  13. How may possible angle FSeF bond angles are present in SeF(4) molecule...

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  14. In IF(6)^(-) and TeF(5)^(-), sum of axial d-orbitals which are used in...

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  15. Among the following, total no. of planar species is : (i) SF(4) " "...

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  16. Calculate the value of " x+y-z" here x,y and z are total number of non...

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  17. Consider the following table Then calculate value of "p+q+r-s-t".

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  18. In phosphorus acid, if X is number of non bonding electron pairs. Y is...

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  19. Calculate the number of p(pi)-d(pi) bond(s) present in SO(4)^(2-) :

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  20. Sum of sigma and pi bonds in NH(4)^(+) cation is ..

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  21. Consider the following orbitals (i)3p(x) (ii)4d(z^(2)) (iii)3d(x^(2)...

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