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Which of the following statements is inc...

Which of the following statements is incorrect for `PCl_(5)` ?

A

Its three P-Cl bond lengths are equal

B

It involves `sp^(3)` d hybridization

C

It has an regular geometry

D

Its shpae is trigonal bipyramidal

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statement is incorrect for \( PCl_5 \), we will analyze the properties and characteristics of the molecule step by step. ### Step 1: Determine the Valence Electrons Phosphorus (P) has 5 valence electrons, and each chlorine (Cl) atom has 7 valence electrons. Since there are 5 chlorine atoms, the total number of valence electrons in \( PCl_5 \) is: \[ \text{Total valence electrons} = 5 + (5 \times 7) = 5 + 35 = 40 \text{ electrons} \] ### Step 2: Bond Pair and Lone Pair Calculation In \( PCl_5 \), phosphorus forms five bonds with the five chlorine atoms. Therefore: - Bond pairs = 5 - Lone pairs = 0 ### Step 3: Hybridization Hybridization can be determined using the formula: \[ \text{Hybridization} = \text{Number of bond pairs} + \text{Number of lone pairs} \] Thus, the hybridization of \( PCl_5 \) is: \[ \text{Hybridization} = 5 + 0 = 5 \quad \Rightarrow \quad \text{sp}^3\text{d} \] ### Step 4: Molecular Geometry The geometry of \( PCl_5 \) can be described as trigonal bipyramidal. In this structure: - There are three chlorine atoms in the equatorial plane forming a triangle. - Two chlorine atoms are positioned axially, one above and one below the equatorial plane. ### Step 5: Analyze the Statements Now we need to evaluate the statements provided regarding \( PCl_5 \): 1. **Statement 1**: The hybridization of \( PCl_5 \) is sp³d. (Correct) 2. **Statement 2**: The molecular shape is trigonal bipyramidal. (Correct) 3. **Statement 3**: The geometry is regular. (Incorrect) 4. **Statement 4**: The bond lengths are equal in the equatorial plane. (Correct) ### Conclusion The incorrect statement regarding \( PCl_5 \) is: **Statement 3**: The geometry is regular.
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