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Which species below has the same general...

Which species below has the same general shape as `NH_(3)`?

A

`SO_(3)^(2-)`

B

`CO_(3)^(2-)`

C

`NO_(3)^(-)`

D

`SO_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which species has the same general shape as NH₃ (ammonia), we can follow these steps: ### Step 1: Analyze the structure of NH₃ - **Valence Electrons**: Nitrogen (N) has 5 valence electrons, and each hydrogen (H) has 1 valence electron. Therefore, NH₃ has: - \(5 + 3 \times 1 = 8\) valence electrons. - **Lewis Structure**: In NH₃, nitrogen forms three single bonds with three hydrogen atoms and has one lone pair of electrons. - **Steric Number**: The steric number is calculated as the number of bonded atoms plus the number of lone pairs. Here, it is: - \(3 \text{ (bond pairs)} + 1 \text{ (lone pair)} = 4\). - **Hybridization**: With a steric number of 4, the hybridization is \(sp^3\). - **Shape**: The shape of NH₃ is trigonal pyramidal due to the presence of one lone pair. ### Step 2: Identify the species to compare We need to find which of the given species has a similar structure (trigonal pyramidal) to NH₃. ### Step 3: Analyze the given species 1. **SO₃ (sulfur trioxide)**: - Sulfur (S) has 6 valence electrons and forms three double bonds with oxygen. It has no lone pairs. Therefore, its steric number is 3, and it has a trigonal planar shape. 2. **CO₃²⁻ (carbonate ion)**: - Carbon (C) has 4 valence electrons and forms three sigma bonds with oxygen. It has no lone pairs. Its steric number is also 3, leading to a trigonal planar shape. 3. **SO₄²⁻ (sulfate ion)**: - Sulfur (S) has 6 valence electrons and forms four sigma bonds with oxygen. It has no lone pairs. Its steric number is 4, leading to a tetrahedral shape. 4. **NH₃ (ammonia)**: - As analyzed, it has a trigonal pyramidal shape. ### Step 4: Conclusion The species that has the same general shape as NH₃ is **SO₂ (sulfur dioxide)**, which is not listed in the options but is similar to NH₃ in terms of having a lone pair and a trigonal pyramidal shape. ### Final Answer The species that has the same general shape as NH₃ is **SO₂**.

To determine which species has the same general shape as NH₃ (ammonia), we can follow these steps: ### Step 1: Analyze the structure of NH₃ - **Valence Electrons**: Nitrogen (N) has 5 valence electrons, and each hydrogen (H) has 1 valence electron. Therefore, NH₃ has: - \(5 + 3 \times 1 = 8\) valence electrons. - **Lewis Structure**: In NH₃, nitrogen forms three single bonds with three hydrogen atoms and has one lone pair of electrons. - **Steric Number**: The steric number is calculated as the number of bonded atoms plus the number of lone pairs. Here, it is: - \(3 \text{ (bond pairs)} + 1 \text{ (lone pair)} = 4\). ...
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Knowledge Check

  • Isostructrual species are those which have the same shape and hybridisation. Among the given identify the isostructural pairs.

    A
    `[NF_(3) and BF_(3)]`
    B
    `[BF_(4)^(-) and NH_(4)^(+)]`
    C
    `[BCl_(3) and BrCl_(3)]`
    D
    `[NH_(3) and NO_(3)^(-)]`
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