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Which species below has the same general...

Which species below has the same general shape as `NH_(3)`?

A

`SO_(3)^(2-)`

B

`CO_(3)^(2-)`

C

`NO_(3)^(-)`

D

`SO_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which species has the same general shape as NH₃ (ammonia), we can follow these steps: ### Step 1: Analyze the structure of NH₃ - **Valence Electrons**: Nitrogen (N) has 5 valence electrons, and each hydrogen (H) has 1 valence electron. Therefore, NH₃ has: - \(5 + 3 \times 1 = 8\) valence electrons. - **Lewis Structure**: In NH₃, nitrogen forms three single bonds with three hydrogen atoms and has one lone pair of electrons. - **Steric Number**: The steric number is calculated as the number of bonded atoms plus the number of lone pairs. Here, it is: - \(3 \text{ (bond pairs)} + 1 \text{ (lone pair)} = 4\). - **Hybridization**: With a steric number of 4, the hybridization is \(sp^3\). - **Shape**: The shape of NH₃ is trigonal pyramidal due to the presence of one lone pair. ### Step 2: Identify the species to compare We need to find which of the given species has a similar structure (trigonal pyramidal) to NH₃. ### Step 3: Analyze the given species 1. **SO₃ (sulfur trioxide)**: - Sulfur (S) has 6 valence electrons and forms three double bonds with oxygen. It has no lone pairs. Therefore, its steric number is 3, and it has a trigonal planar shape. 2. **CO₃²⁻ (carbonate ion)**: - Carbon (C) has 4 valence electrons and forms three sigma bonds with oxygen. It has no lone pairs. Its steric number is also 3, leading to a trigonal planar shape. 3. **SO₄²⁻ (sulfate ion)**: - Sulfur (S) has 6 valence electrons and forms four sigma bonds with oxygen. It has no lone pairs. Its steric number is 4, leading to a tetrahedral shape. 4. **NH₃ (ammonia)**: - As analyzed, it has a trigonal pyramidal shape. ### Step 4: Conclusion The species that has the same general shape as NH₃ is **SO₂ (sulfur dioxide)**, which is not listed in the options but is similar to NH₃ in terms of having a lone pair and a trigonal pyramidal shape. ### Final Answer The species that has the same general shape as NH₃ is **SO₂**.

To determine which species has the same general shape as NH₃ (ammonia), we can follow these steps: ### Step 1: Analyze the structure of NH₃ - **Valence Electrons**: Nitrogen (N) has 5 valence electrons, and each hydrogen (H) has 1 valence electron. Therefore, NH₃ has: - \(5 + 3 \times 1 = 8\) valence electrons. - **Lewis Structure**: In NH₃, nitrogen forms three single bonds with three hydrogen atoms and has one lone pair of electrons. - **Steric Number**: The steric number is calculated as the number of bonded atoms plus the number of lone pairs. Here, it is: - \(3 \text{ (bond pairs)} + 1 \text{ (lone pair)} = 4\). ...
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VK JAISWAL ENGLISH-CHEMICAL BONDING (BASIC)-SUBJECTIVE PROBLEMS
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  2. Consider following compounds A to E : (A) XeF(n) " " (B) XeF((n+1)...

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  3. Consider the following five group (According to modern periodic table)...

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  4. Consider the following species and find out total number of species wh...

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  5. Consider the following table regarding interhalogen compounds, XY(n) (...

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  6. What is covalency of chlorine atom in second excited state ?

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  7. Sum of sigma and pi bonds in NH(4)^(+) cation is ..

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  8. Calculate the value of X-Y, for XeOF(4). (X=Number of sigma bond pair ...

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  9. The molecule ABn is planar with six pairs of electrons around A in the...

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  10. Calculate value of (X+Y+Z)/(10), here X is O-N-O bond angle in NO(3)^(...

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  11. Calculate x+y+z for H(3)PO(3) acid, where x is no. of lone pairs, y is...

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  12. How many right angle, bond angles are present in TeF(5)^(-) molecular ...

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  13. How may possible angle FSeF bond angles are present in SeF(4) molecule...

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  14. In IF(6)^(-) and TeF(5)^(-), sum of axial d-orbitals which are used in...

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  15. Among the following, total no. of planar species is : (i) SF(4) " "...

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  16. Calculate the value of " x+y-z" here x,y and z are total number of non...

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  17. Consider the following table Then calculate value of "p+q+r-s-t".

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  18. In phosphorus acid, if X is number of non bonding electron pairs. Y is...

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  19. Calculate the number of p(pi)-d(pi) bond(s) present in SO(4)^(2-) :

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  20. Sum of sigma and pi bonds in NH(4)^(+) cation is ..

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  21. Consider the following orbitals (i)3p(x) (ii)4d(z^(2)) (iii)3d(x^(2)...

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