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According to VSEPR theory, in which spec...

According to VSEPR theory, in which species do all the atoms lie in the same plane ?
`1. CH_(3)^(+) " " 2. CH_(3)^(-)`

A

1 only

B

2 only

C

both 1 and 2

D

neither 1 nor 2

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given species has all atoms lying in the same plane according to VSEPR theory, we will analyze the structures of CH₃⁺ (methyl cation) and CH₃⁻ (methyl anion). ### Step-by-Step Solution: 1. **Identify the Valence Electrons:** - Carbon (C) is in group 14 and has 4 valence electrons. - For CH₃⁺, the positive charge means it has lost one electron, leaving it with 3 valence electrons. - For CH₃⁻, the negative charge means it has gained one electron, giving it 5 valence electrons. 2. **Draw the Lewis Structures:** - **For CH₃⁺:** - Carbon is bonded to three hydrogen atoms. - The structure will show carbon at the center with three hydrogen atoms around it. - There are no lone pairs on the carbon atom. - **For CH₃⁻:** - Carbon is bonded to three hydrogen atoms and has one lone pair. - The structure will show carbon at the center with three hydrogen atoms and a lone pair above or below the carbon. 3. **Calculate the Steric Number:** - **For CH₃⁺:** - Steric number = Number of sigma bonds + Number of lone pairs = 3 sigma bonds + 0 lone pairs = 3. - **For CH₃⁻:** - Steric number = 3 sigma bonds + 1 lone pair = 4. 4. **Determine Hybridization:** - **For CH₃⁺:** - With a steric number of 3, the hybridization is sp². - **For CH₃⁻:** - With a steric number of 4, the hybridization is sp³. 5. **Identify the Geometry:** - **For CH₃⁺:** - The geometry is trigonal planar, which means all atoms (C and H) lie in the same plane. - **For CH₃⁻:** - The geometry is trigonal pyramidal due to the presence of the lone pair, which means not all atoms lie in the same plane. ### Conclusion: - **CH₃⁺ (methyl cation)** has all its atoms in the same plane (trigonal planar). - **CH₃⁻ (methyl anion)** does not have all its atoms in the same plane due to the lone pair (trigonal pyramidal). Thus, the answer is **1. CH₃⁺**.

To determine which of the given species has all atoms lying in the same plane according to VSEPR theory, we will analyze the structures of CH₃⁺ (methyl cation) and CH₃⁻ (methyl anion). ### Step-by-Step Solution: 1. **Identify the Valence Electrons:** - Carbon (C) is in group 14 and has 4 valence electrons. - For CH₃⁺, the positive charge means it has lost one electron, leaving it with 3 valence electrons. - For CH₃⁻, the negative charge means it has gained one electron, giving it 5 valence electrons. ...
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  • Which is the most suitable reagent among the following to distinguish compound (3) from rest of the compund? 1. CH_(3)-C-=C-CH_(3) 2. CH_(3)-CH_(2)-CH_(2)-CH_(3) 3. CH_(3)CH_(2)-C-=CH 4. CH_(3)-CH=CH_(2)

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