Home
Class 12
CHEMISTRY
Assertion : 2^(nd) period elements do no...

Assertion : `2^(nd)` period elements do not involve in excitation of electron.
Reason : `2^(nd)` period elements do not have vacant 2d-orbitals.

A

If assertion is true but the reason is false

B

If assertion is false but reason is true

C

IF both assertion and reason are true and the reason is the correct explanation of assertion

D

If both assertion and reason are true but reason is not the correct explanation of assertion

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that "2nd period elements do not involve in excitation of electron." - This means that it claims these elements cannot promote electrons to higher energy levels. 2. **Evaluating the Assertion**: - This statement is **false**. - For example, in carbon (which is a 2nd period element), the electronic configuration is 1s² 2s² 2p². - To form four covalent bonds (like in methane, CH₄), one of the 2s electrons must be excited to the 2p orbital, resulting in four half-filled orbitals that can overlap with hydrogen atoms to form bonds. 3. **Understanding the Reason**: - The reason states that "2nd period elements do not have vacant 2d-orbitals." - This implies that because there are no available d-orbitals in the 2nd period, these elements cannot undergo certain types of electronic transitions. 4. **Evaluating the Reason**: - This statement is **true**. - The 2d orbitals cannot exist because the principal quantum number (n=2) must be greater than the azimuthal quantum number (l=2). Therefore, 2d orbitals are not possible. 5. **Conclusion**: - Since the assertion is false and the reason is true, the correct conclusion is that the assertion does not support the reason. - The correct option is that the assertion is false, and the reason is true. ### Final Answer: - The assertion is false, and the reason is true. Therefore, the correct option is option 2.
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • CHEMICAL BONDING (BASIC)

    VK JAISWAL ENGLISH|Exercise SUBJECTIVE PROBLEMS|54 Videos
  • CHEMICAL BONDING (BASIC)

    VK JAISWAL ENGLISH|Exercise MATCH THE COLUMN|26 Videos
  • CHEMICAL BONDING (ADVANCED)

    VK JAISWAL ENGLISH|Exercise SUBJECTIVE PROBLEMS|64 Videos
  • CO-ORDINATION COMPOUNDS

    VK JAISWAL ENGLISH|Exercise LEVEL 2|144 Videos

Similar Questions

Explore conceptually related problems

Total number of elements of 6th period which have one or more than one 4d electrons :-

Total number of elements of 5th period which have one or more than one 5d electrons :-

Knowledge Check

  • Elements in the first period have valence electrons in

    A
    N shell
    B
    K shell
    C
    M shell
    D
    S shell
  • Similar Questions

    Explore conceptually related problems

    Find the ratio of product of velocity and time period of electron orbiting in 2nd and 3rd stable orbits.

    Write the Boron family elements in the order. Write the electronic configurations of 2^(nd), 3^(rd) and 4^(th) elements of the group.

    Give a reason why period-2 elements are called bridge elements

    The element which has highest 2nd ionisation energy is

    How many elements are there in period 2?

    Assertion: Metallic character increases from left to right among the elements of 2nd period. Reason: Second period is called shortest period.

    What is the number of elements in: 1. 1^(st) period and 2. 2^(nd) period of modern periodic table.