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Assertion : Geometry of IC l(3) is tetra...

Assertion : Geometry of `IC l_(3)` is tetrahedral.
Reason : Its shape is T-shape, due to the presence of two lone pairs.

A

If assertion is true but the reason is false

B

If assertion is false but reason is true

C

IF both assertion and reason are true and the reason is the correct explanation of assertion

D

If both assertion and reason are true but reason is not the correct explanation of assertion

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the assertion and reason provided, we will analyze both statements step by step. ### Step 1: Understand the Assertion The assertion states that the geometry of ICl3 is tetrahedral. **Analysis**: - ICl3, or iodine trichloride, consists of one iodine atom and three chlorine atoms. - Iodine is in group 17 (halogens) and has 7 valence electrons. - When iodine forms ICl3, it shares one electron with each of the three chlorine atoms, resulting in three bonding pairs of electrons. ### Step 2: Determine the Steric Number The steric number is calculated by adding the number of bonded atoms to the number of lone pairs on the central atom (iodine in this case). **Calculation**: - Iodine has 3 bonding pairs (from the three I-Cl bonds). - Iodine also has 2 lone pairs of electrons. - Therefore, the steric number = 3 (bonding pairs) + 2 (lone pairs) = 5. ### Step 3: Identify the Hybridization The hybridization can be determined from the steric number. **Conclusion**: - A steric number of 5 corresponds to sp³d hybridization. ### Step 4: Determine the Molecular Geometry The molecular geometry is influenced by the arrangement of the bonding pairs and lone pairs. **Analysis**: - With 3 bonding pairs and 2 lone pairs, the arrangement of the electron pairs is trigonal bipyramidal. - However, the presence of lone pairs affects the shape. The actual shape of ICl3 is T-shaped due to the repulsion caused by the lone pairs. ### Step 5: Evaluate the Reason The reason states that the shape of ICl3 is T-shaped due to the presence of two lone pairs. **Conclusion**: - This statement is correct. The presence of the two lone pairs results in a T-shaped molecular geometry. ### Final Evaluation - The assertion is false because the geometry of ICl3 is not tetrahedral; it is trigonal bipyramidal. - The reason is true as the shape is indeed T-shaped due to the presence of two lone pairs. ### Final Answer The correct answer is that the assertion is false and the reason is true.
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