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The geometry with respect to the central...

The geometry with respect to the central atom of the following molecules are :
`N(SiH_(3))_(3):Me_(3)N: (SiH_(3))_(3)P`

A

planar, pyramidal, planar

B

planar, pyramidal, pyramidal

C

pyramidal, pyramidal, pyramidal

D

pyramidal, planar, pyramidal

Text Solution

AI Generated Solution

The correct Answer is:
To determine the geometry with respect to the central atom of the molecules \( N(SiH_3)_3 \), \( Me_3N \), and \( (SiH_3)_3P \), we will follow these steps: ### Step 1: Analyze \( N(SiH_3)_3 \) 1. **Identify the central atom**: The central atom is nitrogen (N). 2. **Count the valence electrons**: Nitrogen has 5 valence electrons. 3. **Determine the number of bonds**: There are 3 \( SiH_3 \) groups attached, contributing 3 bond pairs. 4. **Count lone pairs**: Since nitrogen has 5 valence electrons and is forming 3 bonds, it has \( 5 - 3 = 2 \) lone pairs. 5. **Calculate the steric number**: The steric number is the sum of bond pairs and lone pairs: \( 3 \text{ (bond pairs)} + 2 \text{ (lone pairs)} = 5 \). 6. **Determine hybridization**: A steric number of 5 corresponds to \( sp^3d \) hybridization. 7. **Predict geometry**: With \( sp^3d \) hybridization and 2 lone pairs, the geometry is trigonal bipyramidal with a bent shape due to the lone pairs. ### Step 2: Analyze \( Me_3N \) 1. **Identify the central atom**: The central atom is nitrogen (N). 2. **Count the valence electrons**: Nitrogen has 5 valence electrons. 3. **Determine the number of bonds**: There are 3 methyl (Me) groups attached, contributing 3 bond pairs. 4. **Count lone pairs**: Since nitrogen has 5 valence electrons and is forming 3 bonds, it has \( 5 - 3 = 2 \) lone pairs. 5. **Calculate the steric number**: The steric number is \( 3 \text{ (bond pairs)} + 1 \text{ (lone pair)} = 4 \). 6. **Determine hybridization**: A steric number of 4 corresponds to \( sp^3 \) hybridization. 7. **Predict geometry**: With \( sp^3 \) hybridization and 1 lone pair, the geometry is trigonal pyramidal. ### Step 3: Analyze \( (SiH_3)_3P \) 1. **Identify the central atom**: The central atom is phosphorus (P). 2. **Count the valence electrons**: Phosphorus has 5 valence electrons. 3. **Determine the number of bonds**: There are 3 \( SiH_3 \) groups attached, contributing 3 bond pairs. 4. **Count lone pairs**: Since phosphorus has 5 valence electrons and is forming 3 bonds, it has \( 5 - 3 = 2 \) lone pairs. 5. **Calculate the steric number**: The steric number is \( 3 \text{ (bond pairs)} + 1 \text{ (lone pair)} = 4 \). 6. **Determine hybridization**: A steric number of 4 corresponds to \( sp^3 \) hybridization. 7. **Predict geometry**: With \( sp^3 \) hybridization and 1 lone pair, the geometry is trigonal pyramidal. ### Summary of Geometries - \( N(SiH_3)_3 \): Trigonal bipyramidal (bent) - \( Me_3N \): Trigonal pyramidal - \( (SiH_3)_3P \): Trigonal pyramidal

To determine the geometry with respect to the central atom of the molecules \( N(SiH_3)_3 \), \( Me_3N \), and \( (SiH_3)_3P \), we will follow these steps: ### Step 1: Analyze \( N(SiH_3)_3 \) 1. **Identify the central atom**: The central atom is nitrogen (N). 2. **Count the valence electrons**: Nitrogen has 5 valence electrons. 3. **Determine the number of bonds**: There are 3 \( SiH_3 \) groups attached, contributing 3 bond pairs. 4. **Count lone pairs**: Since nitrogen has 5 valence electrons and is forming 3 bonds, it has \( 5 - 3 = 2 \) lone pairs. ...
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