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Assertion : C(3)O(2) is non-polar molecu...

Assertion : `C_(3)O_(2)` is non-polar molecule.
Reason : Terminal `pi-bonds of the molecule are lying in different planes.

A

If assertion is true but the reason is false

B

If assertion is false but reason is true

C

If both assertion and reason are true and the reason is the correct explanation of assertion

D

If both assertion and reason are true and the reason is not the correct explanation of assertion

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the assertion and reason provided in the question, we will break down the steps involved in determining the polarity of the molecule \( C_3O_2 \) and the validity of the reasoning. ### Step 1: Understand the Structure of \( C_3O_2 \) - The molecular formula \( C_3O_2 \) suggests that we have three carbon atoms and two oxygen atoms. - The structure can be represented as \( O=C=C=C=O \), which indicates that there are double bonds between the carbon and oxygen atoms. ### Step 2: Draw the Lewis Structure - Draw the Lewis structure of \( C_3O_2 \): - Carbon atoms are bonded to each other with double bonds. - Each terminal carbon is double-bonded to an oxygen atom. - This results in a linear arrangement of atoms: \( O=C=C=C=O \). ### Step 3: Analyze the Molecular Geometry - The geometry of \( C_3O_2 \) is linear due to the arrangement of the double bonds. - In a linear molecule, the dipole moments of the bonds can either cancel out or add up depending on the electronegativity of the atoms involved. ### Step 4: Determine Polarity - The molecule \( C_3O_2 \) has polar bonds (C=O) due to the difference in electronegativity between carbon and oxygen. - However, because the molecule is linear, the dipole moments from the terminal C=O bonds will cancel each other out. - Therefore, \( C_3O_2 \) is a non-polar molecule. ### Step 5: Evaluate the Assertion and Reason - **Assertion**: \( C_3O_2 \) is a non-polar molecule. This is **true**. - **Reason**: Terminal pi-bonds of the molecule are lying in different planes. This is **false** because the molecule is linear, and the pi-bonds do not lie in different planes; they lie in the same plane. ### Conclusion - The assertion is true, but the reason is false. Therefore, the correct answer is that the assertion is true, but the reason is incorrect.
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