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The IUPAC name of Xe[PtF(6)] is:...

The IUPAC name of `Xe[PtF_(6)]` is:

A

Hexafluoroplatinate(VI) xenon

B

Xenonhexafluoroplatinate(IV)

C

Xenonhexafluoroplatinate(VI)

D

Xenoniumhexafluoroplatinum(V)

Text Solution

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The correct Answer is:
To determine the IUPAC name of the coordination compound `Xe[PtF_(6)]`, we can follow these steps: ### Step 1: Identify the components of the compound The compound consists of xenon (Xe) and a platinum complex with six fluoride ligands. The platinum complex can be represented as `[PtF6]`. ### Step 2: Determine the oxidation state of platinum To find the oxidation state of platinum (Pt) in the complex, we can use the following formula: \[ \text{Oxidation state of Pt} + 6 \times (\text{oxidation state of F}) = \text{charge of the complex} \] Fluorine (F) has an oxidation state of -1. Therefore, we can set up the equation: \[ x + 6 \times (-1) = 0 \] Solving for \(x\): \[ x - 6 = 0 \implies x = +6 \] So, the oxidation state of platinum (Pt) in this complex is +6. ### Step 3: Identify the ligands and their names The ligands in this complex are fluoride ions (F^-). According to IUPAC nomenclature, when naming ligands, we use the prefix "fluoro" for fluoride ions. Since there are six fluoride ions, we use the prefix "hexa-". ### Step 4: Combine the names The name of the complex will start with the name of the ligands followed by the name of the metal. Since the oxidation state of platinum is +6, we will use "platin" and add the suffix "-ate" to indicate that it is a complex anion. ### Step 5: Write the full name Putting it all together, we have: - Ligand: Hexafluoro - Metal: Platinum (with the oxidation state indicated as -ate) Thus, the full IUPAC name of the compound `Xe[PtF_(6)]` is: **Xenon hexafluoroplatinate(VI)** ### Final Answer: **Xenon hexafluoroplatinate(VI)** ---
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