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Which of the following compound show opt...

Which of the following compound show optical isomerism?

A

cis-`[CrCl_(3)(NHl_(3))_(3)]`

B

cis-`[Co(NH_(3))_(4)Cl_(2)]^(+)`

C

`[Co(en)_(3)]^(3+)`

D

trans-`[Co(en)_(2)Cl_(2)]^(+)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given compounds shows optical isomerism, we need to analyze the structures of each compound and check for the presence of a plane of symmetry. A compound exhibits optical isomerism if it lacks a plane of symmetry, meaning it cannot be superimposed on its mirror image. ### Step-by-Step Solution: 1. **Identify the Compounds**: The question provides four coordination compounds. We will analyze each one for optical isomerism. 2. **Analyze the First Compound: CrCl3(NH3)3**: - Structure: Chromium is the central metal ion surrounded by three chloride ions and three ammonia molecules. - Symmetry: This compound has a plane of symmetry due to the arrangement of ligands. Therefore, it does not show optical isomerism. 3. **Analyze the Second Compound: Co(NH3)4Cl2**: - Structure: Cobalt is the central metal ion with four ammonia ligands and two chloride ions. - Symmetry: This complex also has a plane of symmetry, which means it does not exhibit optical isomerism. 4. **Analyze the Third Compound: Co(en)3**: - Structure: Cobalt is the central metal ion surrounded by three bidentate ethylenediamine (en) ligands. - Symmetry: This compound lacks a plane of symmetry because the arrangement of the bidentate ligands does not allow for any symmetry plane. Thus, it can show optical isomerism. 5. **Analyze the Fourth Compound: trans-Co(en)2Cl2+**: - Structure: Cobalt is the central metal ion with two bidentate ethylenediamine ligands and two chloride ions in a trans configuration. - Symmetry: In this case, the trans arrangement leads to the presence of a plane of symmetry. Therefore, it does not exhibit optical isomerism. 6. **Conclusion**: Among the given compounds, only Co(en)3 shows optical isomerism because it does not possess a plane of symmetry. ### Final Answer: The compound that shows optical isomerism is **Co(en)3**.

To determine which of the given compounds shows optical isomerism, we need to analyze the structures of each compound and check for the presence of a plane of symmetry. A compound exhibits optical isomerism if it lacks a plane of symmetry, meaning it cannot be superimposed on its mirror image. ### Step-by-Step Solution: 1. **Identify the Compounds**: The question provides four coordination compounds. We will analyze each one for optical isomerism. 2. **Analyze the First Compound: CrCl3(NH3)3**: ...
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Knowledge Check

  • Which of the following compound shows optical isomerism ?

    A
    `CH_(3) CH_(2)CH_(3)`
    B
    `CH_(2)OHCHOHCH_(2)OH`
    C
    `CH_(3)CHOHC_(2)H_(5)`
    D
    None of these
  • Which of the following compounds exhibit optical isomerism?

    A
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    `H_(2)C=C=CH_(2)`
    C
    D
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