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Which of the following compound show opt...

Which of the following compound show optical isomerism?

A

cis-`[CrCl_(3)(NHl_(3))_(3)]`

B

cis-`[Co(NH_(3))_(4)Cl_(2)]^(+)`

C

`[Co(en)_(3)]^(3+)`

D

trans-`[Co(en)_(2)Cl_(2)]^(+)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given compounds shows optical isomerism, we need to analyze the structures of each compound and check for the presence of a plane of symmetry. A compound exhibits optical isomerism if it lacks a plane of symmetry, meaning it cannot be superimposed on its mirror image. ### Step-by-Step Solution: 1. **Identify the Compounds**: The question provides four coordination compounds. We will analyze each one for optical isomerism. 2. **Analyze the First Compound: CrCl3(NH3)3**: - Structure: Chromium is the central metal ion surrounded by three chloride ions and three ammonia molecules. - Symmetry: This compound has a plane of symmetry due to the arrangement of ligands. Therefore, it does not show optical isomerism. 3. **Analyze the Second Compound: Co(NH3)4Cl2**: - Structure: Cobalt is the central metal ion with four ammonia ligands and two chloride ions. - Symmetry: This complex also has a plane of symmetry, which means it does not exhibit optical isomerism. 4. **Analyze the Third Compound: Co(en)3**: - Structure: Cobalt is the central metal ion surrounded by three bidentate ethylenediamine (en) ligands. - Symmetry: This compound lacks a plane of symmetry because the arrangement of the bidentate ligands does not allow for any symmetry plane. Thus, it can show optical isomerism. 5. **Analyze the Fourth Compound: trans-Co(en)2Cl2+**: - Structure: Cobalt is the central metal ion with two bidentate ethylenediamine ligands and two chloride ions in a trans configuration. - Symmetry: In this case, the trans arrangement leads to the presence of a plane of symmetry. Therefore, it does not exhibit optical isomerism. 6. **Conclusion**: Among the given compounds, only Co(en)3 shows optical isomerism because it does not possess a plane of symmetry. ### Final Answer: The compound that shows optical isomerism is **Co(en)3**.

To determine which of the given compounds shows optical isomerism, we need to analyze the structures of each compound and check for the presence of a plane of symmetry. A compound exhibits optical isomerism if it lacks a plane of symmetry, meaning it cannot be superimposed on its mirror image. ### Step-by-Step Solution: 1. **Identify the Compounds**: The question provides four coordination compounds. We will analyze each one for optical isomerism. 2. **Analyze the First Compound: CrCl3(NH3)3**: ...
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VK JAISWAL ENGLISH-CO-ORDINATION COMPOUNDS-LEVEL 2
  1. Which of the following complex compound exhibits cis-trans isomerism?

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  2. Which of the following will have three stereoisomeric forms? (i) [Cr...

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  3. A coordination complex of type MX(2)Y(2) (M-metal ion: X, Y-monodentat...

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  4. The ratio of cis and trans-isomers of the complex [Ma(2)bcde]^(n+-) is...

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  5. [PdCl(2)(PM e(3))(2)] is a diamagnetic complex of Pd(II). How many tot...

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  6. Complex compounds(s) which is optical active and does ot dpeend upon t...

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  7. Choose the correct code regarding, possible number of geometrical isom...

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  8. How many geometrical isomers are possible for complex [Mab(AB)(2)]^(n+...

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  9. [CoCl(2)(NH(3))(4)]^(+)+Cl^(-) to [CoCl(3)(NH(3))(3)]+NH(3). If in thi...

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  10. Select the correct statement about given square planar complex.

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  11. Select the correct code regarding total number of space isomers for th...

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  12. How many geometrical isomerms are possible or [Pd^(2+)(NH(2)-CH(CH(3))...

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  13. How many geometrical isomers are possible [Co(acac)(2)BrCl]^(Theta) ar...

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  14. Which of the following complex compound exhibits geometrical isomerism...

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  15. In which case racemic mixture is obtained on mixing its mirror images ...

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  16. Which of the following compound show optical isomerism?

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  17. Match List-II with List-II and select the correct answer using the cod...

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  18. A complex whose IUPAC name is not correctly writtein is:

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  19. Which of the following is correct IUPAC name of any compolex compound?

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  20. Find out correct IUPAC name of complex compound

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