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Which statements about mercury are corre...

Which statements about mercury are correct?

A

Hg is a liquid metal

B

Hg forms two series of salts

C

Hg forms no amalgam with iron and platinum

D

Hg does not show variable valency

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statements about mercury are correct, let's analyze the properties and characteristics of mercury (Hg) step by step. ### Step-by-Step Solution: 1. **Identify the Atomic Number and Symbol**: - Mercury has an atomic number of 80 and is represented by the symbol Hg. 2. **State the Physical Form**: - Mercury is unique among metals as it is the only metal that is liquid at room temperature. This property makes it useful in thermometers. 3. **Determine Oxidation States**: - Mercury can exhibit two oxidation states: +1 and +2. This means it can form compounds where it has lost one or two electrons. 4. **Electronic Configuration**: - The electronic configuration of mercury is [Xe] 4f14 5d10 6s2. - When it loses one electron to form Hg+, it becomes [Xe] 4f14 5d10 6s1. - When it loses two electrons to form Hg2+, it becomes [Xe] 4f14 5d10. 5. **Stability of the d-Orbitals**: - The fully filled d-orbitals (5d10) in mercury contribute to its stability, which is why it does not typically exhibit a +3 oxidation state. The stability of the d10 configuration prevents the loss of additional electrons. 6. **Formation of Amalgams**: - Mercury can form amalgams with most metals, which are alloys of mercury with other metals. However, it does not form amalgams with iron and platinum. 7. **Variable Oxidation States**: - Although mercury can show +1 and +2 oxidation states, it does not exhibit variable valency in the same way that some other transition metals do. Therefore, it is not considered to have variable oxidation states. ### Conclusion: Based on the analysis: - Mercury is a transition metal with atomic number 80 (correct). - It is liquid at room temperature (correct). - It forms two oxidation states: +1 and +2 (correct). - It forms amalgams with most metals except iron and platinum (correct). - It does not exhibit variable valency (correct). Thus, all statements about mercury are correct.
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