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The molar heat capacity of a certain sub...

The molar heat capacity of a certain substance varies with temperature according to the given equation
`C=27.2+(4xx10^-3)T`
The heat necessary to change the temperature of 2 mol of the substance from 300 K to 700 K is

A

`3.46xx10^4J`

B

`2.33xx10^3J`

C

`3.46xx10^3J`

D

`2.33xx10^4J`

Text Solution

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The correct Answer is:
To solve the problem, we need to calculate the heat necessary to change the temperature of 2 moles of a substance from 300 K to 700 K, given the molar heat capacity equation \( C = 27.2 + 4 \times 10^{-3} T \). ### Step-by-Step Solution: 1. **Identify the Variables:** - Moles of substance, \( n = 2 \) mol - Initial temperature, \( T_1 = 300 \) K - Final temperature, \( T_2 = 700 \) K - Molar heat capacity, \( C(T) = 27.2 + 4 \times 10^{-3} T \) 2. **Set Up the Heat Equation:** The heat \( Q \) required to change the temperature can be expressed as: \[ Q = n \int_{T_1}^{T_2} C(T) \, dT \] Here, \( C(T) \) is the molar heat capacity which varies with temperature. 3. **Substitute the Molar Heat Capacity into the Integral:** \[ Q = 2 \int_{300}^{700} \left( 27.2 + 4 \times 10^{-3} T \right) \, dT \] 4. **Break Down the Integral:** \[ Q = 2 \left( \int_{300}^{700} 27.2 \, dT + \int_{300}^{700} 4 \times 10^{-3} T \, dT \right) \] 5. **Calculate the First Integral:** \[ \int_{300}^{700} 27.2 \, dT = 27.2 \times (700 - 300) = 27.2 \times 400 = 10880 \] 6. **Calculate the Second Integral:** \[ \int_{300}^{700} 4 \times 10^{-3} T \, dT = 4 \times 10^{-3} \left[ \frac{T^2}{2} \right]_{300}^{700} \] \[ = 4 \times 10^{-3} \left( \frac{700^2}{2} - \frac{300^2}{2} \right) = 4 \times 10^{-3} \left( \frac{490000 - 90000}{2} \right) \] \[ = 4 \times 10^{-3} \left( \frac{400000}{2} \right) = 4 \times 10^{-3} \times 200000 = 800 \] 7. **Combine the Results:** \[ Q = 2 \left( 10880 + 800 \right) = 2 \times 11680 = 23360 \, \text{J} \] 8. **Final Answer:** \[ Q = 2.336 \times 10^4 \, \text{J} \] ### Conclusion: The heat necessary to change the temperature of 2 moles of the substance from 300 K to 700 K is approximately \( 2.33 \times 10^4 \, \text{J} \).

To solve the problem, we need to calculate the heat necessary to change the temperature of 2 moles of a substance from 300 K to 700 K, given the molar heat capacity equation \( C = 27.2 + 4 \times 10^{-3} T \). ### Step-by-Step Solution: 1. **Identify the Variables:** - Moles of substance, \( n = 2 \) mol - Initial temperature, \( T_1 = 300 \) K - Final temperature, \( T_2 = 700 \) K ...
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Knowledge Check

  • An ice cube of mass 0.1 kg at 0^@C is placed in an isolated container which is at 227^@C . The specific heat s of the container varies with temperature T according to the empirical relation s=A+BT , where A= 100 cal//kg.K and B = 2xx 10^-2 cal//kg.K^2 . If the final temperature of the container is 27^@C , determine the mass of the container. (Latent heat of fusion for water = 8xx 10^4 cal//kg , specific heat of water =10^3 cal//kg.K ).

    A
    0.495 kg
    B
    0.595 kg
    C
    0.695 kg
    D
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  • An ice cube of mass 0.1 kg at 0^@C is placed in an isolated container which is at 227^@C . The specific heat s of the container varies with temperature T according to the empirical relation s=A+BT , where A= 100 cal//kg.K and B = 2xx 10^-2 cal//kg.K^2 . If the final temperature of the container is 27^@C , determine the mass of the container. (Latent heat of fusion for water = 8xx 10^4 cal//kg , specific heat of water =10^3 cal//kg.K ).

    A
    `0.495 kg`
    B
    `0.595 kg`
    C
    `0.695 kg`
    D
    `0.795 kg`
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