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Assertion (A) : K(p) is always greater t...

Assertion (A) : `K_(p)` is always greater than `K_(c)`.
Reason (R) : The effect of pressure is greater on the rate of reaction than the effect of concentration.

A

If both (A) and (R) are correct, and (R) is the correct explanation for (A)

B

If both (A) and (R) are correct, but (R) is not the correct explanation of (A)

C

If (A) is correct, but (R) is incorrect

D

If both (A) and (R) are incorrect.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the assertion and reason provided, we can break down the solution into clear steps. ### Step-by-Step Solution: 1. **Understanding the Assertion (A)**: - The assertion states that \( K_p \) is always greater than \( K_c \). - This is a claim that needs to be evaluated based on the relationship between \( K_p \) and \( K_c \). 2. **Understanding the Relationship**: - The relationship between \( K_p \) and \( K_c \) is given by the equation: \[ K_p = K_c (RT)^{\Delta n} \] - Here, \( R \) is the universal gas constant, \( T \) is the temperature in Kelvin, and \( \Delta n \) is the change in the number of moles of gas (moles of products - moles of reactants). 3. **Analyzing \( \Delta n \)**: - The value of \( \Delta n \) can be positive, negative, or zero: - If \( \Delta n > 0 \): This means there are more moles of gas in the products than in the reactants, leading to \( K_p > K_c \). - If \( \Delta n < 0 \): This means there are fewer moles of gas in the products than in the reactants, leading to \( K_p < K_c \). - If \( \Delta n = 0 \): This means the number of moles of gas is the same on both sides, leading to \( K_p = K_c \). 4. **Conclusion on Assertion (A)**: - Since \( K_p \) can be greater than, less than, or equal to \( K_c \) depending on the value of \( \Delta n \), the assertion that \( K_p \) is always greater than \( K_c \) is **false**. 5. **Understanding the Reason (R)**: - The reason states that the effect of pressure is greater on the rate of reaction than the effect of concentration. - This statement is not universally true. The effect of pressure on the rate of reaction depends on the reaction mechanism and the specific conditions of the reaction. 6. **Conclusion on Reason (R)**: - Since the effect of pressure does not always have a greater impact than concentration on the rate of reaction, the reason is also **false**. 7. **Final Conclusion**: - Both the assertion (A) and the reason (R) are false. Therefore, the correct answer to the question is that both statements are incorrect. ### Final Answer: - The assertion (A) is false, and the reason (R) is also false. Therefore, the correct option is **D**: Both assertion and reason are incorrect.

To solve the question regarding the assertion and reason provided, we can break down the solution into clear steps. ### Step-by-Step Solution: 1. **Understanding the Assertion (A)**: - The assertion states that \( K_p \) is always greater than \( K_c \). - This is a claim that needs to be evaluated based on the relationship between \( K_p \) and \( K_c \). ...
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