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The number of Schottky defects (n) prese...

The number of Schottky defects (n) present in an ionic compound containing `N` ions at temperature `T` is given by `n = Ne^(-E//2KT)`, where `E` is the energy required to create `n` Schottky defects and `K` is the Boltzmann constant, If the mole fraction of Schottky defect in `NaCl` crystal at `2900 K` is `X`, then calculate `-ln(x)`,
Given: `DeltaH` of Schottky defect `= 2 eV` and
`K = 1.38 xx 10^(-23) J K^(-1)`
`1 eV = 1.608 xx 10^(-19) J`

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The correct Answer is:
To solve the problem, we will follow the steps outlined in the video transcript, but we will break them down into clearer steps for better understanding. ### Step-by-Step Solution: 1. **Understanding the Formula**: The number of Schottky defects \( n \) is given by the formula: \[ n = N e^{-\frac{E}{2kT}} \] where: - \( N \) = total number of ions - \( E \) = energy required to create Schottky defects (given as \( \Delta H = 2 \, \text{eV} \)) - \( k \) = Boltzmann constant \( = 1.38 \times 10^{-23} \, \text{J/K} \) - \( T \) = temperature in Kelvin (given as \( 2900 \, \text{K} \)) 2. **Convert Energy from eV to Joules**: Since \( 1 \, \text{eV} = 1.608 \times 10^{-19} \, \text{J} \), we convert \( E \): \[ E = 2 \, \text{eV} = 2 \times 1.608 \times 10^{-19} \, \text{J} = 3.216 \times 10^{-19} \, \text{J} \] 3. **Calculate \( \frac{E}{2kT} \)**: Substitute \( E \), \( k \), and \( T \) into the equation: \[ \frac{E}{2kT} = \frac{3.216 \times 10^{-19}}{2 \times (1.38 \times 10^{-23}) \times 2900} \] Calculate \( 2kT \): \[ 2kT = 2 \times 1.38 \times 10^{-23} \times 2900 = 8.004 \times 10^{-20} \, \text{J} \] Now calculate \( \frac{E}{2kT} \): \[ \frac{E}{2kT} = \frac{3.216 \times 10^{-19}}{8.004 \times 10^{-20}} \approx 4.015 \] 4. **Calculate Mole Fraction \( X \)**: The mole fraction \( X \) can be expressed as: \[ X = \frac{n}{N + n} = \frac{N e^{-\frac{E}{2kT}}}{N + N e^{-\frac{E}{2kT}}} = \frac{e^{-\frac{E}{2kT}}}{1 + e^{-\frac{E}{2kT}}} \] Substitute \( e^{-\frac{E}{2kT}} \): \[ e^{-\frac{E}{2kT}} = e^{-4.015} \approx 0.0183 \] Now calculate \( X \): \[ X = \frac{0.0183}{1 + 0.0183} = \frac{0.0183}{1.0183} \approx 0.0180 \] 5. **Calculate \( -\ln(X) \)**: Now, we need to find \( -\ln(X) \): \[ -\ln(0.0180) \approx 4.0 \] ### Final Answer: Thus, the value of \( -\ln(X) \) is approximately \( 4 \).

To solve the problem, we will follow the steps outlined in the video transcript, but we will break them down into clearer steps for better understanding. ### Step-by-Step Solution: 1. **Understanding the Formula**: The number of Schottky defects \( n \) is given by the formula: \[ n = N e^{-\frac{E}{2kT}} ...
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Knowledge Check

  • In the Schottky defect:

    A
    an ion moves to interstitial position between the lattice points
    B
    electrons are trapped in a lattice site
    C
    some lattice sites are vacant
    D
    some extra cations are present in interstitial spaces
  • Schottky defect is likely to be found in

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    B
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    C
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  • Schottky defect is observed in crystals when

    A
    some cations move from their lattice site to interstitial sites
    B
    equal number of cations and anions are missing from the lattice
    C
    some lattice sites are occupied by electrons
    D
    some impurity is present in the lattice
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