Home
Class 12
CHEMISTRY
The order of reaction may be a fractiona...

The order of reaction may be a fractional number.

Text Solution

AI Generated Solution

The correct Answer is:
### Step-by-Step Solution: 1. **Understanding the Order of Reaction**: The order of a reaction refers to the power to which the concentration of a reactant is raised in the rate law expression. It indicates how the rate of reaction is affected by the concentration of the reactants. 2. **Experimental Determination**: The order of a reaction is not something that can be predicted solely from the balanced chemical equation. Instead, it is determined experimentally. This means that to find out the order, one must conduct experiments and analyze the data. 3. **Possible Values of Order**: The order of a reaction can take on various values: - **Positive Order**: Indicates that an increase in the concentration of the reactant increases the rate of reaction. - **Zero Order**: Indicates that changes in the concentration of the reactant do not affect the rate of reaction. - **Negative Order**: Indicates that an increase in the concentration of the reactant decreases the rate of reaction. - **Fractional Order**: It is possible for the order of a reaction to be a fractional number (e.g., 0.5, 1.5). This typically occurs in complex reactions where the relationship between concentration and rate is not straightforward. 4. **Conclusion**: Therefore, the statement that "the order of reaction may be a fractional number" is true. It reflects the complexity of reaction kinetics and the various ways in which reactants can influence the rate of a reaction.
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Multiple Correct|5 Videos
  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Single Correct|19 Videos
  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Fill In The Blanks|37 Videos
  • CARBOXYLIC ACIDS AND THEIR DERIVATIVES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Archives (Analytical And Descriptive)|34 Videos
  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|18 Videos

Similar Questions

Explore conceptually related problems

Order of reaction cannot be fractional.

Assertion (A) : The order of a reaction can be fractional but molecularity is never fractional. Reason (R ): The order of reaction does not depend upon the stoichiometric coefficients of a balanced equation.

Each question contains STATEMENTS-1 (Assertion) and STATEMENT -2 (Reason). Examine the statements carefully and mark the correct answer according to the instructions given below: STATEMENT-1: The order of reaction can have fractional value. STATEMENT-2: For an elementary reaction, the parial orders are determined by the reaction stoichiometry

Every fraction is a rational number.

The order of reaction is decided by

Define order of a reaction.

Knowledge Check

  • The order of reaction is decided by

    A
    temperature
    B
    mechanism of reaction as well as relative concentration of reactants
    C
    molecularity
    D
    pressure.
  • CENGAGE CHEMISTRY ENGLISH-CHEMICAL KINETICS-Exercises True/False
    1. The order of reaction may be a fractional number.

      Text Solution

      |

    2. The molecularity and order of reaction can be 0, 1, 2, etc. True or ...

      Text Solution

      |

    3. The hydrolysis of ester in alkaline medium is a

      Text Solution

      |

    4. All first order reactions are unimolecular. T or F

      Text Solution

      |

    5. All radioactive decompoistion reactions are…………..order reactions.

      Text Solution

      |

    6. Negative catalyst stop chemical reactions. T or F

      Text Solution

      |

    7. Can a catalyst affect the state of chemical equilibrium ?

      Text Solution

      |

    8. A first order reaction has very high value of activation energy. T o...

      Text Solution

      |

    9. The molecularity of a complex reaction is always greater than the orde...

      Text Solution

      |

    10. For a zero order reaction, The rate becomes double when the concentrat...

      Text Solution

      |

    11. For a zero order reaction, the half-life periof is independent of the ...

      Text Solution

      |

    12. x g of a radioactive substance will be decomposed to 7//8x g in 40 s i...

      Text Solution

      |

    13. For a first order reaction, the half-life periof is 0.263 k. T or F

      Text Solution

      |

    14. The sum of powers to which of the concentration terms are raised in th...

      Text Solution

      |

    15. The difference between the energy maximum along a reaction path and th...

      Text Solution

      |

    16. The graph between log k versus 1//T is a straight line.

      Text Solution

      |

    17. The slope of the tangent drawn on velocity-time graph at any instant o...

      Text Solution

      |

    18. A poistive catalyst increases the activation energy of the reaction.

      Text Solution

      |

    19. The slope of straight line in a plot of log.[A] versus time for a firs...

      Text Solution

      |

    20. The rate of reaction increases with increase in activation energy.

      Text Solution

      |