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The hybridisation of C atoms in (C - C) ...

The hybridisation of `C` atoms in `(C - C)` single-bond of `H - C -= C - CH = CH_(2)` is :

A

`H_(2) C = CH - C -= CH`

B

`HC -= C - CH_(2) - C -= CH`

C

`H_(2) C = C = C = CH_(2)`

D

`sp- sp^(2)`

Text Solution

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The correct Answer is:
To determine the hybridization of the carbon atoms in the compound \( H - C \equiv C - C = CH_2 \), we will analyze the bonding and geometry around each carbon atom. ### Step-by-Step Solution: 1. **Identify the Structure**: The given compound can be represented as: \[ H - C \equiv C - C = CH_2 \] Here, we have: - A terminal carbon (C1) bonded to hydrogen (H) and connected to a carbon with a triple bond (C2). - The second carbon (C2) is part of a triple bond with the first carbon (C1) and is also connected to another carbon (C3) with a single bond. - The third carbon (C3) is involved in a double bond with the fourth carbon (C4, which is \( CH_2 \)). 2. **Determine Hybridization of Each Carbon**: - **C1 (Terminal Carbon)**: - C1 is bonded to one hydrogen atom and to C2 (which has a triple bond). - Since it forms one sigma bond with C2 and one bond with H, it has a total of 2 regions of electron density. - Therefore, C1 is **sp hybridized**. - **C2 (Triple Bond Carbon)**: - C2 is involved in a triple bond with C1 and a single bond with C3. - It has a total of 2 regions of electron density (one sigma bond with C3 and one sigma bond from the triple bond with C1). - Therefore, C2 is also **sp hybridized**. - **C3 (Double Bond Carbon)**: - C3 is bonded to C2 (with a single bond) and C4 (with a double bond). - It has a total of 3 regions of electron density (one sigma bond with C2 and one sigma bond plus one pi bond with C4). - Therefore, C3 is **sp² hybridized**. - **C4 (Terminal Carbon)**: - C4 is bonded to C3 with a double bond and two hydrogen atoms. - It has a total of 3 regions of electron density (one sigma bond with C3 and two sigma bonds with H). - Therefore, C4 is also **sp² hybridized**. 3. **Conclusion**: The hybridization of the carbon atoms in the carbon-carbon single bond of \( H - C \equiv C - C = CH_2 \) is **sp hybridized for C1 and C2**, and **sp² hybridized for C3 and C4**. ### Final Answer: The hybridization of the carbon atoms in the carbon-carbon single bond is **sp hybridized** for C1 and C2, and **sp² hybridized** for C3 and C4.

To determine the hybridization of the carbon atoms in the compound \( H - C \equiv C - C = CH_2 \), we will analyze the bonding and geometry around each carbon atom. ### Step-by-Step Solution: 1. **Identify the Structure**: The given compound can be represented as: \[ H - C \equiv C - C = CH_2 ...
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Knowledge Check

  • The hybridisation of carbons of C-C single bond of HC-=C-CH=CH_(2) is

    A
    `sp^(3)-sp^(3)`
    B
    `sp-sp^(2)`
    C
    `sp^(3)-sp`
    D
    `sp^(2)-sp^(3)`
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