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The correct order of IE(2) of C, N, O an...

The correct order of `IE_(2)` of `C, N, O` and `F` is

A

`O gt F gt N gt C`

B

`F gt O gt N gt C`

C

`C gt N gt O gt F`

D

`O gt N gt F gt C`

Text Solution

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The correct Answer is:
To determine the correct order of second ionization energy (IE₂) for carbon (C), nitrogen (N), oxygen (O), and fluorine (F), we will follow these steps: ### Step 1: Write the electronic configurations - **Carbon (C)**: Atomic number = 6 Electronic configuration: 1s² 2s² 2p² - **Nitrogen (N)**: Atomic number = 7 Electronic configuration: 1s² 2s² 2p³ - **Oxygen (O)**: Atomic number = 8 Electronic configuration: 1s² 2s² 2p⁴ - **Fluorine (F)**: Atomic number = 9 Electronic configuration: 1s² 2s² 2p⁵ ### Step 2: Analyze the first ionization energies (IE₁) - For **C**: After removing one electron, it becomes C⁺: 1s² 2s² 2p¹ - For **N**: After removing one electron, it becomes N⁺: 1s² 2s² 2p² - For **O**: After removing one electron, it becomes O⁺: 1s² 2s² 2p³ - For **F**: After removing one electron, it becomes F⁺: 1s² 2s² 2p⁴ ### Step 3: Determine the stability of the resulting ions - **O⁺** has a half-filled 2p subshell (2p³), which is more stable and requires more energy to remove another electron. - **F⁺** also has a stable configuration (2p⁴), but it is less stable than O⁺ because it is one electron away from a stable noble gas configuration. - **N⁺** has a half-filled 2p subshell (2p²), which is stable but less than O⁺. - **C⁺** is the least stable among these because it has a 2p¹ configuration. ### Step 4: Compare the second ionization energies (IE₂) - **IE₂ for O**: Highest due to stability of half-filled subshell. - **IE₂ for F**: Second highest, as it is one electron away from a stable configuration. - **IE₂ for N**: Third, as it has a half-filled subshell but is less stable than O. - **IE₂ for C**: Lowest, as it is the least stable configuration. ### Conclusion: Correct order of IE₂ The correct order of second ionization energy (IE₂) for C, N, O, and F is: **O > F > N > C**

To determine the correct order of second ionization energy (IE₂) for carbon (C), nitrogen (N), oxygen (O), and fluorine (F), we will follow these steps: ### Step 1: Write the electronic configurations - **Carbon (C)**: Atomic number = 6 Electronic configuration: 1s² 2s² 2p² - **Nitrogen (N)**: Atomic number = 7 Electronic configuration: 1s² 2s² 2p³ ...
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