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The correct order of relative stability ...

The correct order of relative stability of half filled and completely filled sub-shell is

A

`p^(3) gt d^(5) lt d^(10) lt p^(6)`

B

`d^(5) gt p^(3) lt d^(10) lt p^(6)`

C

`d^(5) gt p^(3) gt d^(10) gt p^(6)`

D

`p^(3) lt d^(10) lt d^(5) lt p^(6)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct order of relative stability of half-filled and completely filled subshells, we need to analyze the stability of different electron configurations based on the principles of electron filling and stability. ### Step-by-Step Solution: 1. **Understanding Stability of Electron Configurations**: - Half-filled and fully filled subshells are known to have enhanced stability due to symmetry and exchange energy. - A half-filled subshell has all orbitals singly occupied before any orbital is doubly occupied, which maximizes the exchange energy. 2. **Identify the Electron Configurations**: - Let's consider the following configurations: - \( p^3 \) (half-filled p subshell) - \( d^5 \) (half-filled d subshell) - \( d^{10} \) (fully filled d subshell) - \( p^6 \) (fully filled p subshell) 3. **Order of Stability**: - A fully filled subshell is generally more stable than a half-filled subshell. - Among half-filled subshells, \( p^3 \) (which is half-filled) is more stable than \( d^5 \) (which is also half-filled). - Therefore, the order of stability can be summarized as follows: - Fully filled \( p^6 \) > Fully filled \( d^{10} \) > Half-filled \( d^5 \) > Half-filled \( p^3 \) 4. **Final Stability Order**: - Based on the above analysis, the correct order of relative stability is: - \( p^6 > d^{10} > d^5 > p^3 \) 5. **Conclusion**: - Thus, the final answer indicating the correct order of relative stability of half-filled and completely filled subshells is: - \( p^6 > d^{10} > d^5 > p^3 \)

To determine the correct order of relative stability of half-filled and completely filled subshells, we need to analyze the stability of different electron configurations based on the principles of electron filling and stability. ### Step-by-Step Solution: 1. **Understanding Stability of Electron Configurations**: - Half-filled and fully filled subshells are known to have enhanced stability due to symmetry and exchange energy. - A half-filled subshell has all orbitals singly occupied before any orbital is doubly occupied, which maximizes the exchange energy. ...
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