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The electron gain enthalpy of oxygen is ...

The electron gain enthalpy of oxygen is `"______"` that of sulphur.

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To determine the relationship between the electron gain enthalpy of oxygen and sulfur, we need to analyze the electronic configurations and the factors affecting electron gain enthalpy. ### Step-by-Step Solution: 1. **Identify the Electronic Configurations**: - Oxygen (O) has the electronic configuration: \(1s^2 2s^2 2p^4\). - Sulfur (S) has the electronic configuration: \(1s^2 2s^2 2p^6 3s^2 3p^4\). 2. **Understand the Concept of Electron Gain Enthalpy**: - Electron gain enthalpy is the amount of energy released when an electron is added to a neutral atom in the gaseous state. A more negative value indicates a greater tendency to gain an electron. 3. **Analyze the Subshells**: - In oxygen, the added electron goes into the 2p subshell, while in sulfur, it goes into the 3p subshell. - The 2p subshell is smaller in size compared to the 3p subshell. 4. **Consider the Size and Inter-electronic Repulsion**: - The smaller size of the 2p subshell leads to greater inter-electronic repulsion when an additional electron is added. - In sulfur, the 3p subshell is larger, which means the added electron experiences less repulsion from the existing electrons. 5. **Conclusion**: - Due to the smaller size of the 2p subshell and the greater inter-electronic repulsion in oxygen, the electron gain enthalpy of oxygen is less negative (or less favorable) compared to that of sulfur. - Therefore, the electron gain enthalpy of oxygen is **less than** that of sulfur. ### Final Answer: The electron gain enthalpy of oxygen is **less than** that of sulfur.

To determine the relationship between the electron gain enthalpy of oxygen and sulfur, we need to analyze the electronic configurations and the factors affecting electron gain enthalpy. ### Step-by-Step Solution: 1. **Identify the Electronic Configurations**: - Oxygen (O) has the electronic configuration: \(1s^2 2s^2 2p^4\). - Sulfur (S) has the electronic configuration: \(1s^2 2s^2 2p^6 3s^2 3p^4\). ...
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The electron gain enthalpy of oxygen is "…………………." than that of sulphur.

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Assertion: The electron gain enthalpy of N is +ve while that of P is -ve. Reason: Smaller atomic size of N is which there is a considerable electron-electron repulsion and hence the additional electron is not accepted easily.

Why is the electron gain enthalpy of O or F less than that of S or Cl?

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Electron gain enthalpy of fluorine is less than that of chlorine - explain.

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CENGAGE CHEMISTRY ENGLISH-PERIODIC CLASSIFICATION OF ELEMENTS AND GENERAL INORGANIC CHEMISTRY-Exercises (Fill In The Blanks)
  1. IUPAC name for the element with Z = 117 is "" and its symbol is " ".

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  2. In the long form of the perodic table, physical and chemical propertie...

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  3. The first periodic law stated by mendeleev was

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  4. The elements which constitute 5f-block are called " " with atomic numb...

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  5. The elements of group 1,2,13,14,15,16,17,18 are collectively called

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  6. Fill in the blanks by picking the correct option. ...

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  7. Lather Meyer drew a graph showing the relation between atomic "" and ...

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  8. Ionic radii "" with increases in atomic number in a period and "" ...

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  9. The electron gain enthalpy of oxygen is "" that of sulphur.

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  10. On Mulliken scale the average of IP and EA is known as "" .

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  11. On the Pauling's EN scale, the element next to F is ""

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  12. The IE of Be is "" than that of B.

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  13. The bond angle in SO(4)^(2-) ion is "" .

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  14. The angle between two covalent bonds is maximum for (CH(4), H(2)O, CO(...

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  15. Second element of group 1 shows diagonal relationship with the secound...

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  16. The EN of the elements C, N, Si and P increases in the order of "" .

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  17. The decreasing order IE for elements Li, Be, C B is "" .

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  18. The type of magnetism exhibited by [Mn(H(2)O)(6)]^(2+) ion is "" .

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  19. Among the ions Cl^(ɵ), S^(2-) and Na^(o+), the largest ion is "" .

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  20. The inner electrons are shielded to a "" extent than the outer electro...

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