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The electron gain enthalpy of oxygen is ...

The electron gain enthalpy of oxygen is `"______"` that of sulphur.

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To determine the relationship between the electron gain enthalpy of oxygen and sulfur, we need to analyze the electronic configurations and the factors affecting electron gain enthalpy. ### Step-by-Step Solution: 1. **Identify the Electronic Configurations**: - Oxygen (O) has the electronic configuration: \(1s^2 2s^2 2p^4\). - Sulfur (S) has the electronic configuration: \(1s^2 2s^2 2p^6 3s^2 3p^4\). 2. **Understand the Concept of Electron Gain Enthalpy**: - Electron gain enthalpy is the amount of energy released when an electron is added to a neutral atom in the gaseous state. A more negative value indicates a greater tendency to gain an electron. 3. **Analyze the Subshells**: - In oxygen, the added electron goes into the 2p subshell, while in sulfur, it goes into the 3p subshell. - The 2p subshell is smaller in size compared to the 3p subshell. 4. **Consider the Size and Inter-electronic Repulsion**: - The smaller size of the 2p subshell leads to greater inter-electronic repulsion when an additional electron is added. - In sulfur, the 3p subshell is larger, which means the added electron experiences less repulsion from the existing electrons. 5. **Conclusion**: - Due to the smaller size of the 2p subshell and the greater inter-electronic repulsion in oxygen, the electron gain enthalpy of oxygen is less negative (or less favorable) compared to that of sulfur. - Therefore, the electron gain enthalpy of oxygen is **less than** that of sulfur. ### Final Answer: The electron gain enthalpy of oxygen is **less than** that of sulfur.

To determine the relationship between the electron gain enthalpy of oxygen and sulfur, we need to analyze the electronic configurations and the factors affecting electron gain enthalpy. ### Step-by-Step Solution: 1. **Identify the Electronic Configurations**: - Oxygen (O) has the electronic configuration: \(1s^2 2s^2 2p^4\). - Sulfur (S) has the electronic configuration: \(1s^2 2s^2 2p^6 3s^2 3p^4\). ...
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The electron gain enthalpy of oxygen is "…………………." than that of sulphur.

Assertion: magnitude of electron gain enthalpy of oxygen is less than that of fluorine but greater than that of nitrogen. Reason: Ionisation enthalpy order is as follows: N gt O lt E .

Knowledge Check

  • Why is the electron gain enthalpy of O or F less than that of S or Cl?

    A
    O and F are more electronegative than S and Cl.
    B
    When an electron is added to O or F,it goe to a smaller(n=2) level and suffers more repulsion than the electron in S or Cl in larger level(n=3)
    C
    Adding an electron to 3p-orbital leads to more rpulsion than 2p-orbital.
    D
    Electron gain enthalpy depends upon the electron affinity of the atom.
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