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As the s character of the hybrid orbital...

As the `s` character of the hybrid orbital decreases, the `EN` increases.

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To analyze the statement "As the s character of the hybrid orbital decreases, the electronegativity increases," we can follow these steps: ### Step 1: Understand Hybridization Hybridization is the concept where atomic orbitals mix to form new hybrid orbitals. The type of hybridization (sp, sp², sp³) determines the character of the orbitals involved. ### Step 2: Identify s Character in Hybrid Orbitals The s character in hybrid orbitals varies depending on the type of hybridization: - **sp hybridization**: 50% s character - **sp² hybridization**: 33.3% s character - **sp³ hybridization**: 25% s character ### Step 3: Relate s Character to Electronegativity Electronegativity is the ability of an atom to attract shared electrons in a bond. As the s character of the hybrid orbital increases, the electrons are held closer to the nucleus. This proximity enhances the nucleus's ability to attract electrons, thus increasing electronegativity. ### Step 4: Analyze the Statement The statement claims that as the s character decreases, electronegativity increases. However, based on our understanding: - Higher s character (like in sp hybridization) corresponds to higher electronegativity. - Lower s character (like in sp³ hybridization) corresponds to lower electronegativity. ### Step 5: Conclusion The statement is incorrect. As the s character of the hybrid orbital decreases, the electronegativity does not increase; it actually decreases. ### Final Answer The statement "As the s character of the hybrid orbital decreases, the electronegativity increases" is **false**. Higher s character in hybrid orbitals leads to higher electronegativity due to the closer proximity of electrons to the nucleus. ---

To analyze the statement "As the s character of the hybrid orbital decreases, the electronegativity increases," we can follow these steps: ### Step 1: Understand Hybridization Hybridization is the concept where atomic orbitals mix to form new hybrid orbitals. The type of hybridization (sp, sp², sp³) determines the character of the orbitals involved. ### Step 2: Identify s Character in Hybrid Orbitals The s character in hybrid orbitals varies depending on the type of hybridization: - **sp hybridization**: 50% s character ...
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Knowledge Check

  • Assertion: Hybridisation influences the bond length and bond enthalpy in organic compound. Reason: More the s character of hybrid orbital, shorter and stornger will be the bond.

    A
    If both assertion and reason are true and reason is the correct explanation of assertion
    B
    If both assertion and reason are true but reason is not the correct explanation of assertion
    C
    If assertion is true but reason is false.
    D
    If both assertion and reason are false.
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