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Arrange the following as directed (a) ...

Arrange the following as directed
(a) `N_(2),O_(2),F_(2),CI_(2)` (Decreasing order of bond energey )
(b) `S-O,N-CI Mg -O,` As -F (Decreasing polarity of bonds)
(c ) `sp,sp^(2) ,sp` (Decreasing order of energy of orbitals)
(d) `HF, HCI,HBr, HI` (Decreasing order of dipole moments)

Text Solution

Verified by Experts

`N_(2)gtO_(2)gtCI_(2)gtF_(2)` [Triple bond `(-=)` in `N_(2)` is stronger bond than double bond (=) in `O_(2)`] Both `CI_(2)` and `F_(2)` have single bond But due to very small size of F-atoms repulsions between non-bonding `e^(-') s` in `F_(2)` molecule are very high therefore bond strength of `CI_(2)gtF_(2)`
(b) `Mg- O gt As - F gt S - O gt N -CI` (Larger the `EN` of halogen more is the energy
(d) `HF gt HCI gt HBr gt HI` (Larger the `EN` of halogen more is the dipole moment) .
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Knowledge Check

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  • Arrange the following in decreasing order of E_(2) reaction :

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  • CENGAGE CHEMISTRY ENGLISH-CHEMICAL BONDING AND MOLECULAR STRUCTURE-Ex 2 .2 Objective
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    4. Predict the shape of the following Xenon compounds (a) XeO(3) (b) Xe...

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    5. Considering x-axis as the internuclear axis which out of the following...

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    6. Arrange the following types of interaction in order of decreasing st...

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    7. Arrange the following types of intermolecular forces in order of decre...

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    8. Name the types of interaction or intermolecular forces of which potent...

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    9. List properties of water that stem from H-bonding

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    10. Predict the order of decreasing boiling points of the following H(2),H...

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    11. Which of the following pairs is expected to exhibit H-bonding (a) CH...

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    12. (a)Give the decreasing order of melting points of the following NH(3),...

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    13. Give the number of electrons which occupy the bonding orbitals in H(2)...

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    14. Compare the relative stabilities and magnetic behaviour of the followi...

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    15. Expalin (a) H(2)^(o+) and H(2)^(Θ) ions have same bond order but H(2...

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    16. Which of the following species have same bond order and same shape (...

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    17. Which of the following is soluble in water

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    18. Which one among the following does not have the hybrogen bond ?

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    19. The molecule having one unpaired electrons is .

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    20. The hydrogen bond is strongest in

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