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In the reaction : 2X+B(2)H(6) rarr [BH...

In the reaction :
`2X+B_(2)H_(6) rarr [BH_(2)(X_(2))]^(oplus) [BH_(4)]^(Ө)`
Which of the following is not 'X' ?

A

`NH_(3)`

B

`CH_(3)NH_(2)`

C

`(CH_(3))_(2) NH`

D

`(CH_(3))_(3) N`

Text Solution

Verified by Experts

The correct Answer is:
A, B, C
Tertiary amines do not react in this reduction due to bulky methyl groups.
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Knowledge Check

  • In the following reactions 2X+B_(2)H_(6) to [BH_(2)(X)_(2)]^(+){BH_(4)]^(-) The amine X will not be -

    A
    `NH_(3)`
    B
    `CH_(3)NH_(2)`
    C
    `(CH)_(3))_(2) NH`
    D
    `(CH_(3))_(3)n`

  • What are X and Y in the reaction? 3B_(2)H_(6) + 6X to 3[BH_(2) (X)_(2)]^(+) [BH_(4)]^(-) overset("heat")(to) Y + 12 H_(2)

    A
    `X = NH_(3), Y = B_(3)N_(3)H_(6)`
    B
    `X = CO, Y = BH_(3)CO`
    C
    `X = NaH, Y = NaF`
    D
    `X = NF_(3), Y = B_(3)N_(3)`

  • The major product formed in the reaction C_(6)H_(5) - overset(oplus)(N)-=NCl^(oplus) + H_(3)PO_(2) + H_(2)O to is :

    A
    `C_(6)H_(5)OH`
    B
    `C_(6)H_(5)Cl`
    C
    `C_(6)H_(6)`
    D
    `C_(6)H_(5)C_(6)H_(5)`