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What is the bond order of O2 molecule ?...

What is the bond order of `O_2` molecule ?

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To find the bond order of the O₂ molecule, we can follow these steps: ### Step 1: Understand Bond Order Bond order is defined as the number of chemical bonds between a pair of atoms. It can be calculated using the formula: \[ \text{Bond Order} = \frac{1}{2} \times (\text{Number of bonding electrons} - \text{Number of anti-bonding electrons}) \] ### Step 2: Determine the Electron Configuration of Oxygen The atomic number of oxygen (O) is 8, which means each oxygen atom has 8 electrons. The electron configuration for an oxygen atom is: \[ 1s^2 \, 2s^2 \, 2p^4 \] ### Step 3: Write the Molecular Orbital Diagram for O₂ In the O₂ molecule, we have two oxygen atoms, so the total number of electrons is: \[ 8 \, \text{(from one O)} + 8 \, \text{(from another O)} = 16 \, \text{electrons} \] The molecular orbital filling for O₂ is as follows: - 1s: 2 electrons (bonding) - 1s*: 0 electrons (anti-bonding) - 2s: 2 electrons (bonding) - 2s*: 0 electrons (anti-bonding) - 2p: 4 electrons (bonding) - 2p*: 2 electrons (anti-bonding) ### Step 4: Count the Electrons in Bonding and Anti-bonding Orbitals - **Bonding Electrons**: - 1s: 2 - 2s: 2 - 2p: 4 - **Total Bonding Electrons = 2 + 2 + 4 = 8** - **Anti-bonding Electrons**: - 1s*: 0 - 2s*: 0 - 2p*: 2 - **Total Anti-bonding Electrons = 0 + 0 + 2 = 2** ### Step 5: Calculate the Bond Order Using the bond order formula: \[ \text{Bond Order} = \frac{1}{2} \times (\text{Number of bonding electrons} - \text{Number of anti-bonding electrons}) \] \[ \text{Bond Order} = \frac{1}{2} \times (8 - 2) = \frac{1}{2} \times 6 = 3 \] ### Conclusion The bond order of the O₂ molecule is 2. This indicates that there are two bonds between the two oxygen atoms.

To find the bond order of the O₂ molecule, we can follow these steps: ### Step 1: Understand Bond Order Bond order is defined as the number of chemical bonds between a pair of atoms. It can be calculated using the formula: \[ \text{Bond Order} = \frac{1}{2} \times (\text{Number of bonding electrons} - \text{Number of anti-bonding electrons}) \] ### Step 2: Determine the Electron Configuration of Oxygen The atomic number of oxygen (O) is 8, which means each oxygen atom has 8 electrons. The electron configuration for an oxygen atom is: ...
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Knowledge Check

  • The bond order in F_2 molecule is :

    A
    0
    B
    1
    C
    2
    D
    3
  • The bond order of a molecule is given by

    A
    the difference between the number of electrons in bonding and antibonding orbitals.
    B
    total number of electrons in bonding and antibonding orbitals.
    C
    Twice the difference between the number of electrons in bonding and antibonding orbitals.
    D
    Half the difference between umbe of electrons in bonding and antibonding orbitals.
  • Assertion : O_(2) molecule is diamagnetic while C_(2) molecule is paramagnetic in nature. Reason : Bond order of O_(2) molecule is 1.5 and that of C_(2) molecule is 2.5 .

    A
    If both assertion and reason are true and reason is the correct explanation of assertion.
    B
    If both assertion and reason are true but reason in not the correct explanation of assertion.
    C
    If assertion is true but reason is false.
    D
    If both assertion and reason are false.
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    What will be the mass of O_2 molecule in grams?

    L.C.A.O. Principle is involved in the formation of the molecular orbitals according to molecular orbital theory. The energy of the bonding molecular orbital is less than that of the combining atomic orbitals while that of the antibonding molecular orbitals while that of the order (B.O.)=1/2(N_(b)-N_(a)) helps in predicting (i) formation of molecules/molecular ions, bond dissociation energy, stability and bond length. Only the molecules or ions with positive B.O. can be formed. These will be diamagnetic if all molecular orbitals are dilled and paramagnetic if one of more are half filled. The atomic orbitals at the time of overlap must have the same symmetry as well. The bond order (B.O.) in B_(2) molecule is:

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