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Assertion (A): Bond energy of CI-CI bond...

Assertion (A): Bond energy of CI-CI bond is more than F-F bond.
Reason (R ): Shorter the bond length, stronger the bond, more is the bond energy.

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To solve the question regarding the assertion and reason provided, we will analyze each part step by step. ### Step 1: Analyze the Assertion (A) The assertion states that the bond energy of the Cl-Cl bond is more than that of the F-F bond. - **Bond Energy of Halogens**: The bond energies of the halogen diatomic molecules (F2, Cl2, Br2, I2) follow a specific trend. Generally, the bond energy decreases as we move down the group from fluorine to iodine. - **Comparison of Cl-Cl and F-F**: The bond energy of Cl-Cl is indeed higher than that of F-F. This is because, although fluorine has a shorter bond length, the bond energy is also influenced by the repulsion between the lone pairs of electrons on the fluorine atoms, which weakens the bond. **Conclusion for Step 1**: The assertion is correct. ### Step 2: Analyze the Reason (R) The reason states that "shorter the bond length, stronger the bond, more is the bond energy." - **Bond Length and Bond Energy Relationship**: Generally, it is true that shorter bond lengths correspond to stronger bonds, which typically means higher bond energies. However, this relationship can be affected by other factors, such as electron repulsion. - **Specific Case of F-F Bond**: In the case of the F-F bond, although it has a shorter bond length than the Cl-Cl bond, the bond energy is lower due to significant inter-electronic repulsions between the lone pairs of electrons on the two fluorine atoms. **Conclusion for Step 2**: The reason is not entirely accurate in this context because it does not account for the influence of electron repulsion on bond strength and energy. ### Final Conclusion - The assertion (A) is correct: The bond energy of Cl-Cl is indeed more than that of F-F. - The reason (R) is not a correct explanation for the assertion because it overlooks the role of inter-electronic repulsions in the F-F bond. ### Final Answer Assertion (A) is true, and Reason (R) is false. Therefore, the correct answer is that the assertion is correct but the reason is not a valid explanation for the assertion. ---

To solve the question regarding the assertion and reason provided, we will analyze each part step by step. ### Step 1: Analyze the Assertion (A) The assertion states that the bond energy of the Cl-Cl bond is more than that of the F-F bond. - **Bond Energy of Halogens**: The bond energies of the halogen diatomic molecules (F2, Cl2, Br2, I2) follow a specific trend. Generally, the bond energy decreases as we move down the group from fluorine to iodine. - **Comparison of Cl-Cl and F-F**: The bond energy of Cl-Cl is indeed higher than that of F-F. This is because, although fluorine has a shorter bond length, the bond energy is also influenced by the repulsion between the lone pairs of electrons on the fluorine atoms, which weakens the bond. ...
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