Home
Class 12
CHEMISTRY
Why is the separation of lanthanide elem...

Why is the separation of lanthanide elements difficult?

Text Solution

AI Generated Solution

### Step-by-Step Solution: 1. **Understanding Lanthanides**: The lanthanide series consists of 15 elements from lanthanum (La, atomic number 57) to lutetium (Lu, atomic number 71). These elements are known for their similar properties. 2. **Lanthanide Contraction**: The primary reason for the difficulty in separating lanthanide elements is the phenomenon known as "lanthanide contraction." This refers to the gradual decrease in ionic and atomic radii of the lanthanide elements as one moves from lanthanum to lutetium. 3. **Effect of Electron Configuration**: As we progress through the lanthanide series, electrons are added to the 4f subshell. The effective nuclear charge increases due to the addition of protons in the nucleus, which pulls the electrons closer to the nucleus, resulting in a smaller atomic radius. ...
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • APPENDIX INORGANIC VOLUME 2

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises|137 Videos
  • ALIPHATIC AND AROMATIC ALDEHYDES AND KETONES

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|26 Videos
  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective Type|4 Videos

Similar Questions

Explore conceptually related problems

Assign reasons for the following: (a) Zn^(2+) salts are white while Cu^(2+) salts are blue. (b) Separation of lanthanoid elements is difficult. Explain.

Lanthanides are

Knowledge Check

  • Which is the non-lanthanide element ?

    A
    La
    B
    Lu
    C
    Pr
    D
    Pm
  • Which of the following statements concering lanthanide elements is false ?

    A
    All lanthanides are highly dense metals.
    B
    More characteristic oxidation state of lanthanide elements is +3.
    C
    Lanthanides are separated from one another by ion exchange method.
    D
    Ionic radii of tricalent lanthanides stradily increases with increases in the atomic number.
  • Similar Questions

    Explore conceptually related problems

    What is the position of lanthanide and actinide series in the periodic table ?

    Which of lanthanides is man-made element?

    Why is hydrogen regarded as a unique element?

    Why is the extraction of copper from pyrites more difficult than that from its oxide ore through reduction?

    The speration of lanthanides by ion exchanges method is based on

    Why is synthesis of transactinides difficult ?