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Why is the separation of lanthanide elem...

Why is the separation of lanthanide elements difficult?

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### Step-by-Step Solution: 1. **Understanding Lanthanides**: The lanthanide series consists of 15 elements from lanthanum (La, atomic number 57) to lutetium (Lu, atomic number 71). These elements are known for their similar properties. 2. **Lanthanide Contraction**: The primary reason for the difficulty in separating lanthanide elements is the phenomenon known as "lanthanide contraction." This refers to the gradual decrease in ionic and atomic radii of the lanthanide elements as one moves from lanthanum to lutetium. 3. **Effect of Electron Configuration**: As we progress through the lanthanide series, electrons are added to the 4f subshell. The effective nuclear charge increases due to the addition of protons in the nucleus, which pulls the electrons closer to the nucleus, resulting in a smaller atomic radius. ...
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CENGAGE CHEMISTRY ENGLISH-APPENDIX INORGANIC VOLUME 2-Short Answer Type
  1. Assertion : Hydrochloric acid is not used to acidify a KMnO(4) solutio...

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  2. Why Sm^(2+) , Eu^(2+) and Yb^(2+) ions are good reducing agents , but ...

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  3. Why is the separation of lanthanide elements difficult?

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  4. Account for the fact that second ionization energies of both Cr and Cu...

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  5. Name the compound used for measuring the hardness of water, i.e., for ...

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  6. How will you distinguish between the following isomer pairs? (i). [...

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  7. The magnitude of stability constant gives an indication of the stabili...

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  8. What are the most important coordination numbers encountered in coordi...

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  9. Name the central atom present in haemoglobin and chlorophyll.

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  10. the red coloured Wilkinson's catalyst, [RhCl(PPh(3))(3)] is a homogeno...

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  11. What is spectrochemical series? Explain the difference between a weak ...

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  12. The magnitude of CFSE (Crystal Field Splitting Energy , Delta(0)) can ...

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  13. What are t(2g) and e(g) orbitals?

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  14. Give the geometry and magnetic character of [NiBr4]^(2-)

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  15. How is tetrabutyl tim prepared?

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  16. What is the coordination number of Fe in [Fe("edta")]^(-) ?

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  17. Name the two broad categories of organometallic compounds.

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  18. In the formula Fe(eta^(5)-C5H5), what does the prefix eta^(5) denote?

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  19. Name two complexes which are used in medicines.

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  20. Name the ionization isomer of [Cr(H2O)5Br]SO4.

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