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Using curved-arrow notation, show the fo...

Using curved-arrow notation, show the formation of reactive intermediates when the following covalent bonds undergo heterolytic cleavage.
(a) `CH_(3)–SCH_(3)`, (b) `CH_(3)–CN`, (c) `CH_(3)–Cu`

Text Solution

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(Cu is more electropositive than C)
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Using the curved-arrow notation, show the formation of reactive intermediates when the following convalent bonds undergo heterolytic cleavage : (a) CH_3 - S - CH_3 (b) CH_3 - CN ( c) CH_3 - Cu .

Using curved arrow notation show the formation of reaction intermediates when the following covalent bonds undergo heterolysis. (i) H_(3)C-CH_(2)-Cl" " (ii) H_(3)C-C equiv N" " (iii) CH_(3)ONa

Knowledge Check

  • The order of reactivity of CH_(3)CHO, CH_(3)COC_(2)H_(5) and CH_(3)COCH_(3) is

    A
    `CH_(3)CHO gt CH_(3)COCH_(3) gt CH_(3)COC_(2)H_(5)`
    B
    `C_(2)H_(5)COCH_(3) gt CH_(3)COCH_(3) gt CH_(3)CHO`
    C
    `CH_(3)COCH_(3) gt CH_(3)CHO gt C_(2)H_(2)COCH_(3)`
    D
    `CH_(3)COCH_(3) gt C_(2)H_(5)COCH_(3) gt CH_(3)CHO`

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    In CH_(3)CH_(2)OH , the bond that undegoes heterolytic clevage most readily is:

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