1-Propanol and 2- propanol can be distinguished by:

Options

A. a.Oxidation with alkaline `KMnO_(4)` followed by reaction with Fehiling's solution.
B. b.Oxidation with acidic dichromate followed by reaction with Fehling's solution
C. c.Oxidation by heating with copper followed by reaction with Fehling's solution.
D. d.Oxidation with concentrated `H_(2)SO_(4)` follwed by reaction with Fehling's solution.

Explanation

To distinguish between 1-Propanol and 2-Propanol, we can follow these steps:

### Step-by-Step Solution:

1. **Identify the Compounds**:
- 1-Propanol (CH3CH2CH2OH) is a primary alcohol.
- 2-Propanol (CH3CHOHCH3) is a secondary alcohol.

2. **Choose the Oxidizing Method**:
- We will use heating with copper (Cu) as the oxidizing agent at a temperature of 300 degrees Celsius.

3. **Oxidation of 1-Propanol**:
- When 1-Propanol is heated with copper, it gets oxidized to form Propanal (CH3CH2CHO), which is an aldehyde.
- The reaction can be summarized as:
\[ \text{CH}_3\text{CH}_2\text{CH}_2\text{OH} \xrightarrow{\text{Cu, 300°C}} \text{CH}_3\text{CH}_2\text{CHO} \]

4. **Reaction with Fehling's Solution**:
- The resulting Propanal can then be reacted with Fehling's solution.
- Fehling's solution contains copper(II) ions, which are reduced to copper(I) oxide (Cu2O), forming a red precipitate.
- The reaction is:
\[ \text{CH}_3\text{CH}_2\text{CHO} + \text{Fehling's solution} \rightarrow \text{Cu}_2\text{O (red precipitate)} + \text{other products} \]

5. **Oxidation of 2-Propanol**:
- When 2-Propanol is heated with copper, it gets oxidized to form Acetone (CH3COCH3), which is a ketone.
- The reaction can be summarized as:
\[ \text{CH}_3\text{CHOHCH}_3 \xrightarrow{\text{Cu, 300°C}} \text{CH}_3\text{COCH}_3 \]

6. **Reaction with Fehling's Solution**:
- The resulting Acetone does not react with Fehling's solution, meaning no red precipitate is formed.
- Therefore:
\[ \text{CH}_3\text{COCH}_3 + \text{Fehling's solution} \rightarrow \text{no reaction} \]

7. **Conclusion**:
- By comparing the results, we can distinguish between 1-Propanol and 2-Propanol:
- 1-Propanol gives a red precipitate with Fehling's solution.
- 2-Propanol does not give any reaction with Fehling's solution.

### Final Answer:
1-Propanol and 2-Propanol can be distinguished by oxidation with copper followed by reaction with Fehling's solution. 1-Propanol gives a red precipitate, while 2-Propanol does not.